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• W2023351667 abstract "By means of non-resonant microwave absorption in low magnetic fields it is found that the superconducting Tc significantly decreases in 60% 13C isotope substituted K3C60 and Rb3C60. The exponent α of the isotope effect, Tcrmc1/mα, is estimated roughly to be α=1.2–2.25, much higher than predicted by the BCS theory. The intrinsic disorder is observed both in the wide-mass spectrum and the dramatically changed IR spectrum reflecting the inhomogeneous distribution of 13C isotopes in 13C60−n12C60 molecules. The large positive α supports the intramolecular vibronic pairing, and the decrease of the electron-vibron coupling λ due to the disturbed symmetry of Hg modes in mixed 13C60−n12Cn molecules is proposed to contribute to the enhanced α, in addition to the conventional isotope frequency shift." @default.
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• W2023351667 date "1992-04-01" @default.
• W2023351667 modified "2023-09-26" @default.
• W2023351667 title "Enhanced isotope effect in 13C-rich superconducting M C60 (M=K, Rb): support for vibronic pairing" @default.
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• W2023351667 doi "https://doi.org/10.1016/0375-9601(92)91120-g" @default.
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