Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023359008> ?p ?o ?g. }
Showing items 1 to 61 of
61
with 100 items per page.
- W2023359008 endingPage "660" @default.
- W2023359008 startingPage "656" @default.
- W2023359008 abstract "Abstract Rotational-echo double-resonance (REDOR) solid-state NMR spectroscopy exhibits an explicit proton radio frequency (RF) decoupling power dependence. Experimental data using model compounds are shown that demonstrate this; as proton RF decoupling powers are increased, the REDOR difference curves change in shape with the maximum REDOR difference approaching unity. This is an important consideration when fitting data with simulations in an attempt to determine internuclear distances from dipole–dipole couplings. Often, the desired decoupling powers that achieve convergence of REDOR difference curves require proton RF powers outside the capabilities of conventional MAS solid-state probes. To alleviate this problem, the two-pulse phase-modulated (TPPM) pulse train is applied during the mixing period of the REDOR pulse sequence. The results show improved efficiency of proton decoupling when TPPM is employed, as compared to the continuous wave case at the same decoupling RF strength. Simulations of a four spin–1/2 system qualitatively agree with the experiments." @default.
- W2023359008 created "2016-06-24" @default.
- W2023359008 creator A5014367967 @default.
- W2023359008 creator A5043787933 @default.
- W2023359008 date "1998-08-01" @default.
- W2023359008 modified "2023-10-10" @default.
- W2023359008 title "Improved heteronuclear decoupling in REDOR with the use of TPPM" @default.
- W2023359008 cites W1966910457 @default.
- W2023359008 cites W1967102339 @default.
- W2023359008 cites W1982890970 @default.
- W2023359008 cites W1986056572 @default.
- W2023359008 doi "https://doi.org/10.1016/s0009-2614(98)00728-3" @default.
- W2023359008 hasPublicationYear "1998" @default.
- W2023359008 type Work @default.
- W2023359008 sameAs 2023359008 @default.
- W2023359008 citedByCount "17" @default.
- W2023359008 countsByYear W20233590082012 @default.
- W2023359008 crossrefType "journal-article" @default.
- W2023359008 hasAuthorship W2023359008A5014367967 @default.
- W2023359008 hasAuthorship W2023359008A5043787933 @default.
- W2023359008 hasConcept C121332964 @default.
- W2023359008 hasConcept C127413603 @default.
- W2023359008 hasConcept C133731056 @default.
- W2023359008 hasConcept C147597530 @default.
- W2023359008 hasConcept C185592680 @default.
- W2023359008 hasConcept C192562407 @default.
- W2023359008 hasConcept C205606062 @default.
- W2023359008 hasConcept C46141821 @default.
- W2023359008 hasConcept C66974803 @default.
- W2023359008 hasConcept C92381491 @default.
- W2023359008 hasConceptScore W2023359008C121332964 @default.
- W2023359008 hasConceptScore W2023359008C127413603 @default.
- W2023359008 hasConceptScore W2023359008C133731056 @default.
- W2023359008 hasConceptScore W2023359008C147597530 @default.
- W2023359008 hasConceptScore W2023359008C185592680 @default.
- W2023359008 hasConceptScore W2023359008C192562407 @default.
- W2023359008 hasConceptScore W2023359008C205606062 @default.
- W2023359008 hasConceptScore W2023359008C46141821 @default.
- W2023359008 hasConceptScore W2023359008C66974803 @default.
- W2023359008 hasConceptScore W2023359008C92381491 @default.
- W2023359008 hasIssue "4-6" @default.
- W2023359008 hasLocation W20233590081 @default.
- W2023359008 hasOpenAccess W2023359008 @default.
- W2023359008 hasPrimaryLocation W20233590081 @default.
- W2023359008 hasRelatedWork W1585871976 @default.
- W2023359008 hasRelatedWork W1833283710 @default.
- W2023359008 hasRelatedWork W1972649478 @default.
- W2023359008 hasRelatedWork W2013440339 @default.
- W2023359008 hasRelatedWork W2102587929 @default.
- W2023359008 hasRelatedWork W2899084033 @default.
- W2023359008 hasRelatedWork W2935759653 @default.
- W2023359008 hasRelatedWork W2950674560 @default.
- W2023359008 hasRelatedWork W3105167352 @default.
- W2023359008 hasRelatedWork W54078636 @default.
- W2023359008 hasVolume "292" @default.
- W2023359008 isParatext "false" @default.
- W2023359008 isRetracted "false" @default.
- W2023359008 magId "2023359008" @default.
- W2023359008 workType "article" @default.