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- W2023360781 abstract "Bei der Umsetzung von Acetamidin H2NC(CH3)NH mit CS2 bei −15°C entsteht das Acetamidiniumsalz der N-Acetimidoyldithiocarbamidsäure. Es reagiert mit Hydroxiden zu den entsprechenden N-Acetimidoyldithiocarbamaten. Die Eigenschaften und das thermische Verhalten der hergestellten Verbindungen documentclass{article}pagestyle{empty}begin{document}$ {rm M}[{rm S}_2 {rm C} - {rm N} = {rm C}({rm CH}_{rm 3} ) - {rm NH}_2 ]{rm mit M} = [({rm H}_2 {rm N})_2 {rm C} - {rm CH}_3 ],{rm Na} cdot {rm CH}_3 {rm OH},{rm K} cdot {rm H}_2 {rm O},{rm Rb},{rm Cs},{rm Tl},{rm Pb}/2{rm und Cd}/2 cdot {rm H}_2 {rm O} $end{document} werden beschrieben. Die Zersetzung in Lösung wurde bei 20°C kinetisch untersucht. On Chalcogenolates. 172. Reaction of Acetamidine with Carbon Disulfide. 1. Synthesis and Properties of N-Acetimidoyl Dithiocarbamates The reaction of acetamidine H2NC(CH3)NH with CS2 at −15°C yields the acetamidinium salt of N-acetimidoyl dithiocarbamic acid. It reacts with hydroxides to form the corresponding N-acetimidoyl dithiocarbamates. The properties and the thermal behaviour of the prepared compounds documentclass{article}pagestyle{empty}begin{document}$ {rm M}[{rm S}_2 {rm C} - {rm N} = {rm C}({rm CH}_{rm 3} ) - {rm NH}_2 ]{rm with M} = [({rm H}_2 {rm N})_2 {rm C} - {rm CH}_3 ],{rm Na} cdot {rm CH}_3 {rm OH},{rm K} cdot {rm H}_2 {rm O},{rm Rb},{rm Cs},{rm Tl},{rm Pb}/2{rm and Cd}/2 cdot {rm H}_2 {rm O} $end{document} have been described. The decomposition in solution has been studied at 20°C kinetically." @default.
- W2023360781 created "2016-06-24" @default.
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- W2023360781 date "1986-06-01" @default.
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- W2023360781 title "�ber Chalkogenolate. 172. Reaktion von Acetamidin mit Kohlenstoffdisulfid 1. Darstellung und Eigenschaften von N-Acetimidoyldithiocarbamaten" @default.
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- W2023360781 doi "https://doi.org/10.1002/zaac.19865370620" @default.
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