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- W2023363407 endingPage "5180" @default.
- W2023363407 startingPage "5175" @default.
- W2023363407 abstract "Abstract Two isostructural compounds, {[Cu 2 (DF) 2 H 2 O] 2 SiW 12 O 40 } · 2H 2 O ( 1 ) and {[Cu 2 (DF) 2 H 2 O] 2 GeMo 12 O 40 } · 2H 2 O ( 2 ) (DF = 4,5‐diazafluoren‐9‐one), were synthesized and characterized by routine methods and single‐crystal X‐ray diffraction. In the compounds, each Keggin cluster links five copper dimers [Cu 2 (DF) 2 H 2 O] 2+ in an unusual asymmetrical pentacoordination mode to form 3D networks with left‐ and right‐handed helical chains. Notably, by comparing 1 and 2 with other helical compounds with Keggin clusters as connectors, we found that the pitches of those compounds are mainly dominated by the coordination modes of the Keggin clusters, suggesting that the Keggin clusters are pitch‐tunable synthons. Furthermore, the luminescent and electrochemical properties of the title compound were studied. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)" @default.
- W2023363407 created "2016-06-24" @default.
- W2023363407 creator A5001008433 @default.
- W2023363407 creator A5003314041 @default.
- W2023363407 creator A5004201951 @default.
- W2023363407 creator A5005245760 @default.
- W2023363407 creator A5035259025 @default.
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- W2023363407 creator A5054852294 @default.
- W2023363407 creator A5055275469 @default.
- W2023363407 creator A5082859400 @default.
- W2023363407 date "2009-11-17" @default.
- W2023363407 modified "2023-09-27" @default.
- W2023363407 title "Two New Helical Compounds Based on Pitch‐Tunable Keggin Clusters" @default.
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