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- W2023363531 abstract "Durch Festkörperreaktionen von TeO2 mit MnO, CoO bzw. NiO unter N2 wurden folgende Verbindungen erhalten und durch Röntgen-Pulverdaten charakterisiert: MTe6O13 (M = Mn, Co), MTe2O5 und M2Te3O8 (M = Mn, Ni), MnTeO3 und M4Te3O10(M = Mn, Co), Mn2Te3O8 und Ni2Te3O8 kristallisieren monoklin mit Zn2Te3O8-Struktur. Untereinander und mit den jeweils entsprechenden Magnesiumverbindungen strukturell eng verwandt oder isotyp sind ferner die Verbindungen MTe6O13 einerseits und M4Te3O10 andererseits. Von den letzteren ist nur Co4Te3O10 stabil, während Mn4Te3O10 bereits unter seinen Bildungsbedingungen langsam zu Tellur, Mn3TeO6 und MnTeO3 disproportioniert. Eine Beziehung zwischen den Gitterenergien von Oxiden MO und ihren Reaktionen mit TeO2 wird diskutiert. By solid state reactions of TeO2 with MnO, CoO, and NiO under nitrogen, the following compounds were obtained and characterized by X-ray powder data: MTe6O13 (M = Mn, Co), MTe2O5 and M2Te3O8 (M = Mn, Ni), MnTeO3, and M4Te3O10, (M = Mn, Co) Mn2Te3O8 and Ni2Te3O8 crystallize with the monoclinic Zn2Te3O8 structure. In respect of their structure, the compounds MTe6O13 and M4Te3O10 are closely related to, or isostructural with, the corresponding magnesium compounds. Under the conditions of its formation. Mn4Te3O10 slowly disproportionates to tellurium, Mn3TeO6 and MnTeO3. A relation between the lattice energies of oxides MO and their reactions with TeO2 is discussed." @default.
- W2023363531 created "2016-06-24" @default.
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- W2023363531 date "1972-01-01" @default.
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- W2023363531 title "Tellurite des zweiwertigen Mangans, Kobalts und Nickels" @default.
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- W2023363531 doi "https://doi.org/10.1002/zaac.19723870210" @default.
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