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- W2023367037 abstract "A critical evaluation of high temperature proton conductors (HTPCs) which might be considered in SOFC applications is presented. A comparison of the conductivities of the best oxygen ion conductors with those of prominent HTPCs shows that a few of the latter may possibly compete in the temperature range 500–700°C. The HTPCs considered here were (a) the classical doped SrCeO3, (b) doped BaCeO3, (c) doped Sr and Ba zirconates, and (d) complex perovskites of type Ba3Ca1.18Nb1.82O9−δ. The compounds favored are those with a high enthalpy of solution of water. Generally, the following materials parameters are desirable: deviation from exact oxygen stoichiometry δ≈0.05; enthalpy of solution of water −ΔHS≥1.5 eV; effective activation energy for proton transport EHeff<=0.55 eV and proton transport number tH≈1." @default.
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- W2023367037 date "1997-05-01" @default.
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- W2023367037 title "Criteria for the application of high temperature proton conductors in SOFCs" @default.
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- W2023367037 doi "https://doi.org/10.1016/s0167-2738(97)00028-3" @default.
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