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• W2023367263 abstract "This Letter reports the evidences for intramolecular six-membered N–H···O hydrogen bonding in N-benzyl benzamides and five-membered N–H···N hydrogen bonding in N-(pyridin-2-ylmethyl) benzamide. Intramolecular six-membered N–H···X (X = O or F) hydrogen bonding in 2-methoxyl- or 2-fluorobenzamides is used to lock the amide proton from forming strong intermolecular N–H···OC hydrogen bonding. As a result, for the first time the new intramolecular hydrogen bonding patterns are observed in the crystal structures of nine amides, whereas the whole molecules give rise to a new class of three-center hydrogen bonding motif. 1H NMR study in chloroform-d also supports that this weak intramolecular hydrogen bonding pattern exists in solution." @default.
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• W2023367263 date "2009-01-01" @default.
• W2023367263 modified "2023-10-01" @default.
• W2023367263 title "Intramolecular N–H···O and N–H···N hydrogen bonding patterns in N-benzyl and N-(pyridin-2-ylmethyl) benzamides" @default.
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• W2023367263 doi "https://doi.org/10.1016/j.tetlet.2008.11.001" @default.
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