Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023367610> ?p ?o ?g. }
Showing items 1 to 73 of
73
with 100 items per page.
- W2023367610 endingPage "82" @default.
- W2023367610 startingPage "75" @default.
- W2023367610 abstract "Tetrakis(trichlorsilyl)silan (neo-Si5Cl12) wird in SiCl4-Lösung mit HCl gezielt zu Tris(trichlorsilyl)silan, HSi(SiCl3)3 und SiCl4 abgebaut. HSi(SiCl3)3 und Bis(trichlorsilyl)silan, H2Si(SiCl3)2, sind auch durch Umsetzungen der entsprechenden Methoxyverbindungen-HSi[Si(OCH3)3]3 und H2Si[Si(OCH3)3]2 mit BCl3 in guter Ausbeute darstellbar. Die Massen-, 1H-NMR- und Schwingungsspektren von HSi(SiCl3)3 und H2Si(SiCl3)2 sowie einige 1H-NMR-Daten von HClSi(SiCl3)2, HCl2SiSiCl3 und H2ClSiSiCl3 werden mitgeteilt und diskutiert. Für neo-Si5Cl12 werden verbesserte Synthesebedingungen angegeben. Preparation and Properties of Some Highly Chlorinated Oligosilanes Tetrakis(trichlorosilyl)silane (neo-Si5Cl12) is cleaved by HCl in SiCl4 solution to tris(trichlorosilyl)silane, HSi(SiCl3)3, and SiCl4. HSi(SiCl3)3 and bis(trichlorosilyl)silane, H2Si(SiCl3)2, can also be prepared in good yield by reaction of the methoxy compounds HSi[Si(OCH3)3]3 and H2Si[Si(OCH3)3]2 with BCl3. The mass, 1H-n.m.r., and vibrational spectra of HSi(SiCl3)3 and H2Si(SiCl3) as well as some 1H-n.m.r. data of HClSi(SiCl3)2, HCl2SiSiCl3 and H2ClSiSiCl3 are reported and discussed. An improved synthesis for neo-Si5Cl12 is given." @default.
- W2023367610 created "2016-06-24" @default.
- W2023367610 creator A5029487195 @default.
- W2023367610 creator A5040126765 @default.
- W2023367610 creator A5045993382 @default.
- W2023367610 date "1977-01-01" @default.
- W2023367610 modified "2023-10-18" @default.
- W2023367610 title "Darstellung und Eigenschaften einiger Hochchlorierter Oligosilane" @default.
- W2023367610 cites W1480744836 @default.
- W2023367610 cites W1964412053 @default.
- W2023367610 cites W1977501219 @default.
- W2023367610 cites W1979453358 @default.
- W2023367610 cites W1983780659 @default.
- W2023367610 cites W1989471113 @default.
- W2023367610 cites W1993869417 @default.
- W2023367610 cites W2000188783 @default.
- W2023367610 cites W2002251028 @default.
- W2023367610 cites W2014770441 @default.
- W2023367610 cites W2016149426 @default.
- W2023367610 cites W2026859837 @default.
- W2023367610 cites W2049699488 @default.
- W2023367610 cites W2052238603 @default.
- W2023367610 cites W2054872263 @default.
- W2023367610 cites W2059932973 @default.
- W2023367610 cites W2061399611 @default.
- W2023367610 cites W2085246285 @default.
- W2023367610 cites W2087856029 @default.
- W2023367610 cites W2095221656 @default.
- W2023367610 cites W2949297344 @default.
- W2023367610 cites W2955639139 @default.
- W2023367610 cites W4255768014 @default.
- W2023367610 doi "https://doi.org/10.1002/zaac.19774280109" @default.
- W2023367610 hasPublicationYear "1977" @default.
- W2023367610 type Work @default.
- W2023367610 sameAs 2023367610 @default.
- W2023367610 citedByCount "16" @default.
- W2023367610 countsByYear W20233676102013 @default.
- W2023367610 countsByYear W20233676102017 @default.
- W2023367610 countsByYear W20233676102018 @default.
- W2023367610 countsByYear W20233676102019 @default.
- W2023367610 countsByYear W20233676102021 @default.
- W2023367610 countsByYear W20233676102022 @default.
- W2023367610 crossrefType "journal-article" @default.
- W2023367610 hasAuthorship W2023367610A5029487195 @default.
- W2023367610 hasAuthorship W2023367610A5040126765 @default.
- W2023367610 hasAuthorship W2023367610A5045993382 @default.
- W2023367610 hasConcept C178790620 @default.
- W2023367610 hasConcept C185592680 @default.
- W2023367610 hasConcept C2778024649 @default.
- W2023367610 hasConceptScore W2023367610C178790620 @default.
- W2023367610 hasConceptScore W2023367610C185592680 @default.
- W2023367610 hasConceptScore W2023367610C2778024649 @default.
- W2023367610 hasIssue "1" @default.
- W2023367610 hasLocation W20233676101 @default.
- W2023367610 hasOpenAccess W2023367610 @default.
- W2023367610 hasPrimaryLocation W20233676101 @default.
- W2023367610 hasRelatedWork W1531601525 @default.
- W2023367610 hasRelatedWork W1990781990 @default.
- W2023367610 hasRelatedWork W2345688907 @default.
- W2023367610 hasRelatedWork W2606230654 @default.
- W2023367610 hasRelatedWork W2607424097 @default.
- W2023367610 hasRelatedWork W2748952813 @default.
- W2023367610 hasRelatedWork W2899084033 @default.
- W2023367610 hasRelatedWork W2948807893 @default.
- W2023367610 hasRelatedWork W2951203964 @default.
- W2023367610 hasRelatedWork W2778153218 @default.
- W2023367610 hasVolume "428" @default.
- W2023367610 isParatext "false" @default.
- W2023367610 isRetracted "false" @default.
- W2023367610 magId "2023367610" @default.
- W2023367610 workType "article" @default.