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- W2023371260 abstract "As a continuation of our research of reactions with alicyclic 1,5,9-trione 1 and its polycyclic form 2, we have studied their reactions with binucleophiles, e.g., phenylene-1,2-diamine and 2-aminophenol, leading to novel N,O-containing polycyclic compounds. Trione 1 formed double cyclization products 11 and 12 with 2-aminophenol and triple cyclization product 15 with phenylene-1,2-diamine. Hemiacetal 2 and its dehydration product 5 reacted with binucleophiles through initial isomerization into the intermediate cyclic form 4 of trione 1. Thus, ketone 5 reacted with 2-aminophenol stereoselectively unlike the hemiacetal 2. The structure and configuration of the reaction products were studied by using advanced spectroscopic techniques including 1D- and 2D-NMR experiments." @default.
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- W2023371260 date "2009-07-01" @default.
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- W2023371260 title "The Structure and Configuration of Novel Polycyclic Products Derived from an Alicyclic 1,5,9-Trione and Binucleophiles" @default.
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- W2023371260 doi "https://doi.org/10.1002/hlca.200800444" @default.
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