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- W2023373342 abstract "Molecular self-assembly offers an effective method to modify the surface properties of common biomaterials by presenting biologically relevant chemistry in a controlled, ordered fashion. This work reports on self-assembling triblock molecules containing rigid cholesteryl segments followed by flexible oligomers of L-(lactic acid) and second generation L-lysine dendrons. Second harmonic generation and small angle X-ray scattering indicate these molecules self-assemble into multilayer polar structures when cast from ethyl acetate solutions and segregate into polar polydomains when annealed. These self-assembled layers significantly improve water wettability when coated onto poly(L-lactic acid) fibers. Scaffolds formed from fibers modified by self-assembly enhance adhesion of 3T3 mouse calvaria cells and produce greater population growth rates. These results demonstrate the use of self-assembly to present biologically relevant chemistry on surfaces of biomaterials. Applications of this technology include the modification of substrates for cell culture, tissue engineering, and cell transplantation." @default.
- W2023373342 created "2016-06-24" @default.
- W2023373342 creator A5013220822 @default.
- W2023373342 creator A5050147422 @default.
- W2023373342 creator A5079222349 @default.
- W2023373342 creator A5091627447 @default.
- W2023373342 date "2004-12-01" @default.
- W2023373342 modified "2023-10-14" @default.
- W2023373342 title "Modification of fibrous poly(l-lactic acid) scaffolds with self-assembling triblock molecules" @default.
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- W2023373342 doi "https://doi.org/10.1016/j.biomaterials.2004.01.042" @default.
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