Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023373713> ?p ?o ?g. }
Showing items 1 to 73 of
73
with 100 items per page.
- W2023373713 endingPage "2133" @default.
- W2023373713 startingPage "2133" @default.
- W2023373713 abstract "Ab initio calculations of the relative energies for various structures and electronic states of the C3N+ ion have been performed and the results used to interpret the C3N+ ionization efficiency curve measured by the ‘near-monochromatic’ electron-impact ionization of cyanoacetylene, HC3N. The calculated lowest-energy isomer, which is reconciled with the experimental appearance energy of the C3N+ ion at 17.78 ± 0.08 eV, is a 3Σ– state of the CCCN+ isomer, corresponding to an experimentally determined C3N+ enthalpy of formation of 1850 kJ mol–1. A sharp break in the experimental ionization efficiency curve 0.9 eV above the appearance energy is in accord with the formation of a cyclic C3N+ isomer which is calculated to lie 1.0 eV above the ground state. There is no conclusive experimental support for the electron-impact formation of the isocyano CCNC+ isomers, which are calculated to lie 0.15 and 0.50 eV above the ground state." @default.
- W2023373713 created "2016-06-24" @default.
- W2023373713 creator A5003822703 @default.
- W2023373713 creator A5013220002 @default.
- W2023373713 date "1987-01-01" @default.
- W2023373713 modified "2023-10-18" @default.
- W2023373713 title "The structure and energetics of the C3N+ ion" @default.
- W2023373713 doi "https://doi.org/10.1039/f29878302133" @default.
- W2023373713 hasPublicationYear "1987" @default.
- W2023373713 type Work @default.
- W2023373713 sameAs 2023373713 @default.
- W2023373713 citedByCount "16" @default.
- W2023373713 countsByYear W20233737132013 @default.
- W2023373713 countsByYear W20233737132014 @default.
- W2023373713 countsByYear W20233737132016 @default.
- W2023373713 crossrefType "journal-article" @default.
- W2023373713 hasAuthorship W2023373713A5003822703 @default.
- W2023373713 hasAuthorship W2023373713A5013220002 @default.
- W2023373713 hasConcept C121332964 @default.
- W2023373713 hasConcept C145148216 @default.
- W2023373713 hasConcept C147192597 @default.
- W2023373713 hasConcept C147368240 @default.
- W2023373713 hasConcept C147789679 @default.
- W2023373713 hasConcept C178790620 @default.
- W2023373713 hasConcept C183971685 @default.
- W2023373713 hasConcept C184779094 @default.
- W2023373713 hasConcept C185592680 @default.
- W2023373713 hasConcept C198291218 @default.
- W2023373713 hasConcept C205759337 @default.
- W2023373713 hasConcept C2777361479 @default.
- W2023373713 hasConcept C2781442258 @default.
- W2023373713 hasConcept C3288061 @default.
- W2023373713 hasConcept C32909587 @default.
- W2023373713 hasConcept C69523127 @default.
- W2023373713 hasConcept C97355855 @default.
- W2023373713 hasConceptScore W2023373713C121332964 @default.
- W2023373713 hasConceptScore W2023373713C145148216 @default.
- W2023373713 hasConceptScore W2023373713C147192597 @default.
- W2023373713 hasConceptScore W2023373713C147368240 @default.
- W2023373713 hasConceptScore W2023373713C147789679 @default.
- W2023373713 hasConceptScore W2023373713C178790620 @default.
- W2023373713 hasConceptScore W2023373713C183971685 @default.
- W2023373713 hasConceptScore W2023373713C184779094 @default.
- W2023373713 hasConceptScore W2023373713C185592680 @default.
- W2023373713 hasConceptScore W2023373713C198291218 @default.
- W2023373713 hasConceptScore W2023373713C205759337 @default.
- W2023373713 hasConceptScore W2023373713C2777361479 @default.
- W2023373713 hasConceptScore W2023373713C2781442258 @default.
- W2023373713 hasConceptScore W2023373713C3288061 @default.
- W2023373713 hasConceptScore W2023373713C32909587 @default.
- W2023373713 hasConceptScore W2023373713C69523127 @default.
- W2023373713 hasConceptScore W2023373713C97355855 @default.
- W2023373713 hasIssue "11" @default.
- W2023373713 hasLocation W20233737131 @default.
- W2023373713 hasOpenAccess W2023373713 @default.
- W2023373713 hasPrimaryLocation W20233737131 @default.
- W2023373713 hasRelatedWork W2006403711 @default.
- W2023373713 hasRelatedWork W2021329692 @default.
- W2023373713 hasRelatedWork W2023373713 @default.
- W2023373713 hasRelatedWork W2062141764 @default.
- W2023373713 hasRelatedWork W2080737672 @default.
- W2023373713 hasRelatedWork W2345101664 @default.
- W2023373713 hasRelatedWork W2390142483 @default.
- W2023373713 hasRelatedWork W2951659545 @default.
- W2023373713 hasRelatedWork W3026276529 @default.
- W2023373713 hasRelatedWork W2948140677 @default.
- W2023373713 hasVolume "83" @default.
- W2023373713 isParatext "false" @default.
- W2023373713 isRetracted "false" @default.
- W2023373713 magId "2023373713" @default.
- W2023373713 workType "article" @default.