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• W2023374828 startingPage "8066" @default.
• W2023374828 abstract "The persistence and degradation of rotenone and its primary degradation product 12aβ-hydroxyrotenone in soils were determined under standardized laboratory conditions in the dark at 20 or 10 °C and at 40% of water holding capacity. Degradation experiments were carried out on two types of soil collected in southern Italy, a silt clay loam (SCL) and a loamy soil (L). A kinetic model was developed to describe degradation rates of rotenone, taking into account the production, retention, and degradation of the main metabolites. The DT50 values of rotenone and 12aβ-hydroxyrotenone, were 8 and 52 days in SCL soil, and 5 and 23 days in L soil at 20 °C, respectively. However, at 10 °C a tendency for slower degradation of rotenone and 12aβ-hydroxyrotenone was observed (25 and 118 days in SCL and 21 and 35 days in L soils, respectively). The differences were significant for most data sets. Temperature had a strong effect on degradation; a 10 °C increase in temperature resulted in a decrease in the DT50 value by a factor of 3.1 and 2.2 in SCL and of 4.2 and 1.4 in L soils for both rotenone and 12aβ-hydroxyrotenone, respectively. Results show that the degradation rates of both rotenone and 12aβ-hydroxyrotenone were greatly affected by temperature changes and soil physicochemical properties. The degradation reaction fits the two compartment or the multiple compartment model pathways better, which clearly indicates a rather complex rotenone degradation process in soils. Results provide further insights on the rates and the mechanisms of rotenone degradation in soils, aiming to more clearly describe the degradation pathway of chemical residues in the environment." @default.
• W2023374828 created "2016-06-24" @default.
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• W2023374828 creator A5040213590 @default.
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• W2023374828 date "2008-08-06" @default.
• W2023374828 modified "2023-09-27" @default.
• W2023374828 title "Degradation and Persistence of Rotenone in Soils and Influence of Temperature Variations" @default.
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• W2023374828 doi "https://doi.org/10.1021/jf801461h" @default.
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