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- W2023379458 abstract "Details are provided for the preparation of three 1-oxa-2-silacyclohexanes; namely, 1-oxa-2,2-diphenyl-2silacyclohexane, 1-oxa-2,2-dimethyl-2-silacyclohexane and 1-oxa-2-methyl-2-silacyclohexane from magnesium halide-catalyzed reactions of some dichlorosilanes and magnesium metal in tetrahydrofuran. A thorough discussion of their mechanism of formation is also presented and syntheses of the following compounds are reported for the first time: 1-oxa-2-methyl-2-silacyclohexane (the first reported compound of this type containing a chiral silicon), (4-bromobutoxy)chlorodimethylsilane and (4-bromobutoxy)-chloromethylsilane." @default.
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- W2023379458 date "1974-11-01" @default.
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- W2023379458 title "1-oxa-2-silacyclohexanes: Mechanism of formation from magnesium halide catalyzed reactions of some dichlorosilanes and magnesium metal in tetrahydrofuran" @default.
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- W2023379458 doi "https://doi.org/10.1016/s0022-328x(00)87884-5" @default.
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