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- W2023384242 abstract "Die Desaminierung von endo- und exo-2-Methl-2-aminomethyl-norbornan mit salpetriger Säure sowie die Hydrolyse von endo- und exo-2-Methyl-2-tosloxymethyl-norbornan wird gaschromatographisch untersucht. Das Verhältnis, in dem die durch Wanderung der Bindung C-1, C-2 bzw. der Bindung C-2, C-3 gebildeten tertären Methyl-bicyclo[3.2.1]octanole-3 and -2 entstehen, hängt stark von sterischen Faktoren ab. Aufgrund der Zusammensetzung der Reaktionsprodukte muss die Beteiligung nichtklassischer Bicyclooctyl-Kationen bei diesen Reaktionen ausgeschlossen werden. The deamination of endo- and exo-2-methyl-2-aminomethyl-norbornane with nitrous acid and the hydrolysis of endo- and exo-2-methyl-2-tosyloxymethyl-norbornane has been investigated by gas-chromatography. The ratio of tertiary methyl-bicyclo[3.2.1.]octanols-3 and -2 formed by carbon shift involving the C-1, C-2 bond and the C-2, C-3 bond, respectively, is chiefly controlled by steric factors. From the prduct composition the conclusion must be drawn that nonclassical bicyclooctyl cations are not involved in the ring expansion reactions." @default.
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- W2023384242 date "1968-01-01" @default.
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- W2023384242 title "Bicyclische Verbindungen—X ringerweiterung von norbornanderivaten—III" @default.
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