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- W2023386719 endingPage "1275" @default.
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- W2023386719 abstract "Für die Olefine 1–8 wurde durch Hydrierwärme-Messung bzw. Kraftfeld-Rechnung die Bildungsenthalpie der Grundzustände und durch kinetische Analyse der geometrischen Isomerisierung die der Übergangszustände ermittelt. Die um fast 30 kcal/mol variierenden Rotationsenthalpien lassen sich mit einer einheitlichen, vom Substitutionsgrad unabhängigen Torsionsbarriere (65.9 ± 0.9 kcal/mol) beschreiben, wenn um die sterischen Energiebeiträge der Grund- und Übergangszustand korrigiert wird. Rotational Barriers of Strained Olefines For the olefins 1–8 heats of formation have been derived from heats of hydrogenation and force-field calculations, respectively. From the kinetics of their geometrical isomerisation the corresponding values for the transition states were obtained. The rotational barriers, which vary by nearly 30 kcal/mol, can be described by a unique torsional potential (65.9 ± 0.9 kcal/mol), which is independent of the degree of substitution, if a correction is made for the steric energy contribution in the ground- and transition-states." @default.
- W2023386719 created "2016-06-24" @default.
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- W2023386719 date "1989-07-01" @default.
- W2023386719 modified "2023-09-29" @default.
- W2023386719 title "Rotationsbarrieren gespannter Olefine" @default.
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- W2023386719 doi "https://doi.org/10.1002/cber.19891220710" @default.
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