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- W2023393835 abstract "Abstract Ultra-violet and visible absorption spectra were obtained for binary solutions of titanium tetrachloride with several aromatic compounds of varying electron density on the ring. These spectra show evidence for a charge-transfer process in such systems. Quantitative absorption studies were conducted on the benzene, anisole, and diphenyl ether containing systems. Attempts to describe the data with Benesi-Hildebrand type equations were successful for the two ether-containing systems by assuming 1 : 1 complexes in the diphenyl ether and both 1 : 1 and 1 : 2 complexes in the anisole system. The benzene system shows no evidence for the formation of a complex. The absorption spectrum in this system is ascribed to contact charge-transfer absorption." @default.
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- W2023393835 date "1965-09-01" @default.
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- W2023393835 title "Spectrophotometric investigation of the interactions in solutions of TiCl4 with several aromatic hydrocarbons and ethers" @default.
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- W2023393835 doi "https://doi.org/10.1016/0022-1902(65)80056-2" @default.
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