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- W2023397079 abstract "The reaction of methyl 4,6-O-benzylidene-2-deoxy-α-d-erythro-hexopyranoside-3-ulose with methyllithium and ethyl- and ethynylmagnesium bromide yielded predominantly the adducts methyl 4,6-O-benzylidene-2-deoxy-3-C-methyl-α-d-ribo-hexopyranoside, methyl 4,6-O-benzylidene-2-deoxy-3-C-ethyl-α-d-ribo-hexopyranoside, and methyl 4,6-O-benzylidene-2-deoxy-3-C-ethynyl-α-d-ribo-hexopyranoside. Similarly, methyl 4,6-O-benzylidene-3-deoxy-α-d-erythro-hexopyranoside-2-ulose gave exclusively methyl 4,6-O-benzylidene-3-deox-2-C-ethyl-α-d-ribo-hexopyranoside. Potential 1,4-dialdehyde building blocks for anthracyclinone synthesis were obtained in both enantiomeric forms from these precursors." @default.
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- W2023397079 date "1987-07-01" @default.
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- W2023397079 title "Chiral building blocks from methyl α-d-mannopyranoside and methyl α-d-glucopyranoside for anthracyclinone synthesis" @default.
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- W2023397079 doi "https://doi.org/10.1016/0008-6215(87)80119-2" @default.
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