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- W2023397887 abstract "Self-assembly of the partially fluorinated rigid molecules physisorbed at solution/graphite interface has been investigated by scanning tunneling microscopy. Upon adsorption, both the branched star-shaped compound 1 and the angulate rod 2 compromising diacetylene and acetylene interlinked benzene and pentafluorobezene formed two-dimensional chiral porous networks. The spontaneous formation of these architectures is likely attributed to the two effects: the compensation of the dipole moments of the branches and the formation of Ar-H...F hydrogen bonds. These results demonstrate that the immobilization of molecules at the liquid/solid interface can be driven by these weak intermolecular interactions instead of van der Waals interactions between alkyl chains and substrate." @default.
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- W2023397887 date "2008-07-24" @default.
- W2023397887 modified "2023-09-25" @default.
- W2023397887 title "Two Dimensional Chiral Networks Emerging from the Aryl−F···H Hydrogen-Bond-Driven Self-Assembly of Partially Fluorinated Rigid Molecular Structures" @default.
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- W2023397887 doi "https://doi.org/10.1021/ja801925q" @default.
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