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• W2023398515 abstract "Ten substituted μ-oxo-bis[tetraphenylporphinatomanganese (III)] compounds ([TRPPMnIII]2O) were synthesized by the reaction of chloro[tetraphenylporphinatomanganese(III)] (TRPPMnIIICl) with NaOH. Their catalysis of cyclohexane monooxygenation by PhIO under moderate conditions was studied. In contrast with other metalloporphyrins reported so far, μ-oxo-bis[tetraphenylporphinatomanganese(III)] compounds are shown to have better catalytic power for cyclohexane hydroxylation by PhIO. The kinetic research showed that the rate constants k of the cyclohexane reactions had a Hammett relationship to the characteristic constants σ of substituents R on porphyrin rings." @default.
• W2023398515 created "2016-06-24" @default.
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• W2023398515 date "1999-07-01" @default.
• W2023398515 modified "2023-09-26" @default.
• W2023398515 title "Study of Synthesis of μ-Oxo-bismanganese(III)Porphyrin Compounds and Their Catalysis of Cyclohexane Oxidation by PhIO" @default.
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• W2023398515 doi "https://doi.org/10.1006/jcat.1999.2496" @default.
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