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- W2023398568 abstract "The infrared spectra of normal and deuterium-enriched Ne:NH3=1600:1 deposits at 4.3 K have been observed, and the structure associated with almost all of the vibrational fundamentals has been assigned. Although the most prominent absorptions arise from the ground-state J=0 level(s), incomplete nuclear-spin equilibration enhances the contribution of absorptions arising from the ground-state J=1 levels. As had been proposed in an earlier study, the inversion splitting for the ν2 fundamental is appreciably reduced from that observed for the gas-phase molecule, and the rotational structure associated with the J=1 levels of the vibrationally excited molecule is somewhat perturbed. Ammonia is trapped in two different types of site in solid neon. Matrix shifts from the corresponding gas-phase absorptions amount to only a few cm−1, and are smaller than those previously reported for ammonia trapped in an argon matrix." @default.
- W2023398568 created "2016-06-24" @default.
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- W2023398568 date "2004-12-01" @default.
- W2023398568 modified "2023-10-16" @default.
- W2023398568 title "The infrared spectrum of NH3-dn trapped in solid neon" @default.
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- W2023398568 doi "https://doi.org/10.1016/j.jms.2004.05.008" @default.
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