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- W2023398979 abstract "Abstract— Thymine and uracil were chemically altered when irradiated with UV light in aqueous solution containing tryptophan as a photosensitizer. The reaction is inhibited by oxygen and is therefore not an example of photodynamic action. Unlike the pyrimidine bases, purine bases were not altered under similar reaction conditions. Two major photoproducts were identified. One of the products was identified as the reduced base, dihydrouracil or dihydrothymine. The quantum yield for formation of dihydrouracil was 0.24 times 10--4 to 13.6 times 10--4, depending upon the concentrations of uracil and the reaction temperature. Radical scavengers such as cysteine and nitrous oxide decreased the rate of dihydrouracil formation. Other indole compounds also sensitized the photoreduction of uracil, their quantum yields ranging from <1 × 10--5 for tryptamine to 1.3 times 10--3 for indole-3-acetic acid. A reaction mechanism is presented whereby the pyrimidines are reduced by electron transfer from a metastable charge transfer complex originating from the first excited singlet state of tryptophan." @default.
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- W2023398979 date "1979-12-01" @default.
- W2023398979 modified "2023-09-24" @default.
- W2023398979 title "PHOTOSENSITIZED REDUCTION OF PYRIMIDINE BASES BY TRYPTOPHAN" @default.
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- W2023398979 doi "https://doi.org/10.1111/j.1751-1097.1979.tb07198.x" @default.
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