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• W2023402942 abstract "The vibrational displacements and isotropic Raman linewidths of the v1 (CH3 symmetric stretching) mode of 1,1,1-trichloroethane (TCE) have been measured in a number of solvents of diverse molecular properties. It was determined that the gas-solution frequency shifts are proportional to the solvent's polarizability, and thus could be interpreted on the basis of solution variations in the London dispersion forces. The isotropic linewidths, on the other hand, were found to be uncorrelated to solvent polarizability, indicating that dispersion interactions are not an important relaxation mechanism. On the other hand, a qualitative correlation was observed between bandwidth and the dipole moment of the solvent, suggesting that dipolar interactions may play a significant role in the line broadening of methyl group vibrations. An alternative explanation of the observed behavior was furnished by the Isolated Binary Collision model, which assumes that vibrational relaxation arises from collisionally modulated repulsive interactions in the liquid. A good correlation was observed between experimental linewidths and widths predicted by the IBC model." @default.
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• W2023402942 date "1988-01-01" @default.
• W2023402942 modified "2023-09-23" @default.
• W2023402942 title "Raman study of peak frequencies and linewidths of the vi mode of trichloroethane in solution" @default.
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• W2023402942 doi "https://doi.org/10.1016/0584-8539(88)80258-7" @default.
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