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- W2023403223 abstract "The radical copolymerization of limonene with acrylonitrile in DMF at 70±0.1°C for 3 hrs, initiated by benzoyl peroxide, yields nonequimolar alternating copolymer(s). The kinetic expression is, Rp∝[I]0.5[AN]1.0[Lim.]−1.0. The overall activation energy is calculated as 26 kJ/mole−1. The formation of copolymer(s) is evidenced by FTIR as it shows bands at 2241.37 cm−1 and 2925.07 cm−1 due to the cyanide group of acrylonitrile and aromatic C–H stretching band of limonene, respectively. H1NMR spectra shows a peak at 5.0 δ due to a trisubstituted olefinic protons of limonene. The values of reactivity ratios r1 (AN)=0.0228 and r2 (Lim)=0.0062 using Kelen–Tüdos method are evaluated. The Alfrey–Price, Q-e parameter for limonene was calculated as 0.27 and −0.87, respectively." @default.
- W2023403223 created "2016-06-24" @default.
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- W2023403223 date "2003-01-07" @default.
- W2023403223 modified "2023-09-23" @default.
- W2023403223 title "Radical Copolymerization of Limonene with Acrylonitrile: Kinetics and Mechanism" @default.
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- W2023403223 doi "https://doi.org/10.1081/ppt-120017966" @default.
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