Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023403354> ?p ?o ?g. }
Showing items 1 to 77 of
77
with 100 items per page.
- W2023403354 endingPage "10872" @default.
- W2023403354 startingPage "10866" @default.
- W2023403354 abstract "We contribute to the development of steady state thermodynamics for isothermal and homogeneous chemical systems, through a generalized Einstein fluctuation relation, by utilizing a local steady state interpretation of static concentration fluctuations of reaction intermediates. For systems of constrained total chemical affinity the ‘‘next-particle ratio’’ of the probability density, q=P(N+1)/P(N), derived from a usual chemical master equation is employed for the construction of chemical potential steady state laws. This analysis is based on the identification of the exponent of the distribution, as a generalized availability of local fluctuations. Further, pressure steady state laws are derived through a generalized Gibbs–Duhem equation, restricted to constant ‘‘disequilibrium variables.’’ Such variables are introduced as state variables, in addition to the classic ones, for the characterization of steady states. They relate to externally controlled generalized forces or affinities, which induce the flows of mass through the system. Within the local steady state approach, the state laws enable the construction of the generalized availability, as state function for quasisteady state processes beginning from a reference state. This quantity is found to provide a Liapounov function for the deterministic evolution of the system towards stationary states in analogy to a previously developed local equilibrium theory. The analysis is applied to two-variable chemical systems of high stoichiometry change, but should be capable of extension to general hydrodynamic systems." @default.
- W2023403354 created "2016-06-24" @default.
- W2023403354 creator A5014686820 @default.
- W2023403354 date "1994-12-15" @default.
- W2023403354 modified "2023-09-23" @default.
- W2023403354 title "Steady state thermodynamics for homogeneous chemical systems" @default.
- W2023403354 cites W1567382983 @default.
- W2023403354 cites W1985894272 @default.
- W2023403354 cites W1991707780 @default.
- W2023403354 cites W2012499538 @default.
- W2023403354 cites W2030247390 @default.
- W2023403354 cites W2035079473 @default.
- W2023403354 cites W2039749153 @default.
- W2023403354 cites W2050218803 @default.
- W2023403354 cites W2058023095 @default.
- W2023403354 cites W2074335683 @default.
- W2023403354 cites W2089789006 @default.
- W2023403354 cites W2090090448 @default.
- W2023403354 cites W2170638518 @default.
- W2023403354 doi "https://doi.org/10.1063/1.467836" @default.
- W2023403354 hasPublicationYear "1994" @default.
- W2023403354 type Work @default.
- W2023403354 sameAs 2023403354 @default.
- W2023403354 citedByCount "2" @default.
- W2023403354 crossrefType "journal-article" @default.
- W2023403354 hasAuthorship W2023403354A5014686820 @default.
- W2023403354 hasConcept C121332964 @default.
- W2023403354 hasConcept C121864883 @default.
- W2023403354 hasConcept C129537906 @default.
- W2023403354 hasConcept C133347239 @default.
- W2023403354 hasConcept C14036430 @default.
- W2023403354 hasConcept C147789679 @default.
- W2023403354 hasConcept C185592680 @default.
- W2023403354 hasConcept C64642268 @default.
- W2023403354 hasConcept C67425144 @default.
- W2023403354 hasConcept C73051877 @default.
- W2023403354 hasConcept C74859849 @default.
- W2023403354 hasConcept C78458016 @default.
- W2023403354 hasConcept C8171440 @default.
- W2023403354 hasConcept C86803240 @default.
- W2023403354 hasConcept C97355855 @default.
- W2023403354 hasConceptScore W2023403354C121332964 @default.
- W2023403354 hasConceptScore W2023403354C121864883 @default.
- W2023403354 hasConceptScore W2023403354C129537906 @default.
- W2023403354 hasConceptScore W2023403354C133347239 @default.
- W2023403354 hasConceptScore W2023403354C14036430 @default.
- W2023403354 hasConceptScore W2023403354C147789679 @default.
- W2023403354 hasConceptScore W2023403354C185592680 @default.
- W2023403354 hasConceptScore W2023403354C64642268 @default.
- W2023403354 hasConceptScore W2023403354C67425144 @default.
- W2023403354 hasConceptScore W2023403354C73051877 @default.
- W2023403354 hasConceptScore W2023403354C74859849 @default.
- W2023403354 hasConceptScore W2023403354C78458016 @default.
- W2023403354 hasConceptScore W2023403354C8171440 @default.
- W2023403354 hasConceptScore W2023403354C86803240 @default.
- W2023403354 hasConceptScore W2023403354C97355855 @default.
- W2023403354 hasIssue "12" @default.
- W2023403354 hasLocation W20234033541 @default.
- W2023403354 hasOpenAccess W2023403354 @default.
- W2023403354 hasPrimaryLocation W20234033541 @default.
- W2023403354 hasRelatedWork W1994887118 @default.
- W2023403354 hasRelatedWork W2023403354 @default.
- W2023403354 hasRelatedWork W2024535138 @default.
- W2023403354 hasRelatedWork W2032151435 @default.
- W2023403354 hasRelatedWork W2074847124 @default.
- W2023403354 hasRelatedWork W2092603494 @default.
- W2023403354 hasRelatedWork W2530041116 @default.
- W2023403354 hasRelatedWork W2898285107 @default.
- W2023403354 hasRelatedWork W2951416388 @default.
- W2023403354 hasRelatedWork W3105387127 @default.
- W2023403354 hasVolume "101" @default.
- W2023403354 isParatext "false" @default.
- W2023403354 isRetracted "false" @default.
- W2023403354 magId "2023403354" @default.
- W2023403354 workType "article" @default.