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- W2023406777 abstract "A mole fraction-based multicomponent thermodynamic model, previously applied to the system H2OH2SO4, is here extended to mixtures with (NH4)2SO4 at 298.15 K. Model parameters are determined by fitting to vapour pressure data (from isopiestic and electrodynamic balance studies), together with degrees of dissociation of the bisulphate ion and salt solubilities (solid phases (NH4)2SO4, (NH4)3H(SO4)2 and NH4HSO4). The model successfully represents the thermodynamic properties of the system to high supersaturation over the full range of composition from (NH4)2SO4H2O to H2SO4H2O. Equilibrium vapour pressures of NH3 have been calculated for mixtures of various compositions." @default.
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- W2023406777 date "1995-01-01" @default.
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- W2023406777 title "A generalised multicomponent thermodynamic model applied to the (NH4)2SO4H2SO4H2O system to high supersaturation and low relative humidity at 298.15 K" @default.
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- W2023406777 doi "https://doi.org/10.1016/0021-8502(94)e0061-2" @default.
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