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- W2023409002 abstract "Abstract Electronic absorption spectra for complexes CpFe(dppe)X [with X = Cl, I and CN; dppe = (Ph) 2 PCH 2 CH 2 P(Ph) 2 ; Cp = η 5 -C 5 H 5 ] and the cationic derivative [CpFe(dppe)NCCH 3 ]PF 6 in different solvents have been measured. The lower energy bands were assigned to iron d - d orbital transitions on the bais of intensities, solvent effects ad extended Huckel MO calculations. The complexes CpFe(dppe)X (with X = Cl and I) undergo ionization in polar solvents to give the cationic solvated species [CpFe(dppe) (solvent)] + . This behaviour can be explained on the basis of the theoretical calculations." @default.
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- W2023409002 date "1993-06-01" @default.
- W2023409002 modified "2023-09-26" @default.
- W2023409002 title "Ionization of the FeX bond in polar solvents: A spectroscopic study of CpFe(dppe)X complexes" @default.
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- W2023409002 doi "https://doi.org/10.1016/s0277-5387(00)84333-8" @default.
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