Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023409044> ?p ?o ?g. }
- W2023409044 endingPage "13759" @default.
- W2023409044 startingPage "13744" @default.
- W2023409044 abstract "We explore several potential issues that have been raised over the years regarding the entropic droplet scenario of activated transport in liquids, due to Wolynes and co-workers, with the aim of clarifying the status of various approximations of the random first-order transition theory (RFOT) of the structural glass transition. In doing so, we estimate the mismatch penalty between alternative aperiodic structures, above the glass transition; the penalty is equal to the typical magnitude of free energy fluctuations in the liquid. The resulting expressions for the activation barrier and the cooperativity length contain exclusively bulk, static properties; in their simplest form they contain only the bulk modulus and the configurational entropy per unit volume. The expressions are universal in that they do not depend explicitly on the molecular detail. The predicted values for the barrier and cooperativity length and, in particular, the temperature dependence of the barrier are in satisfactory agreement with observation. We thus confirm that the entropic droplet picture is indeed not only internally consistent but is also fully constructive, consistent with the apparent success of its many quantitative predictions. A simple view of a glassy liquid as a locally metastable, degenerate pattern of frozen-in stress emerges in the present description. Finally, we derive testable relationships between the bulk modulus and several characteristics of glassy liquids and peculiarities in low-temperature glasses." @default.
- W2023409044 created "2016-06-24" @default.
- W2023409044 creator A5044618101 @default.
- W2023409044 creator A5085437975 @default.
- W2023409044 date "2014-11-13" @default.
- W2023409044 modified "2023-09-28" @default.
- W2023409044 title "On the Mechanism of Activated Transport in Glassy Liquids" @default.
- W2023409044 cites W1646671735 @default.
- W2023409044 cites W1947244720 @default.
- W2023409044 cites W1967303178 @default.
- W2023409044 cites W1969370699 @default.
- W2023409044 cites W1971354120 @default.
- W2023409044 cites W1974409335 @default.
- W2023409044 cites W1976663498 @default.
- W2023409044 cites W1983982839 @default.
- W2023409044 cites W1984553748 @default.
- W2023409044 cites W1989408426 @default.
- W2023409044 cites W1993826366 @default.
- W2023409044 cites W2000216463 @default.
- W2023409044 cites W2001776491 @default.
- W2023409044 cites W2002341782 @default.
- W2023409044 cites W2007487406 @default.
- W2023409044 cites W2008532218 @default.
- W2023409044 cites W2012752527 @default.
- W2023409044 cites W2013140289 @default.
- W2023409044 cites W2017898390 @default.
- W2023409044 cites W2018413904 @default.
- W2023409044 cites W2028457175 @default.
- W2023409044 cites W2029778924 @default.
- W2023409044 cites W2031510975 @default.
- W2023409044 cites W2031641141 @default.
- W2023409044 cites W2032781595 @default.
- W2023409044 cites W2041733563 @default.
- W2023409044 cites W2043443881 @default.
- W2023409044 cites W2050539643 @default.
- W2023409044 cites W2057064411 @default.
- W2023409044 cites W2057206707 @default.
- W2023409044 cites W2067401295 @default.
- W2023409044 cites W2067527883 @default.
- W2023409044 cites W2068873743 @default.
- W2023409044 cites W2070820417 @default.
- W2023409044 cites W2075973109 @default.
- W2023409044 cites W2080276236 @default.
- W2023409044 cites W2084807257 @default.
- W2023409044 cites W2085266415 @default.
- W2023409044 cites W2086166744 @default.
- W2023409044 cites W2092144432 @default.
- W2023409044 cites W2115592565 @default.
- W2023409044 cites W2143128989 @default.
- W2023409044 cites W2166351042 @default.
- W2023409044 cites W2329443640 @default.
- W2023409044 cites W2962847720 @default.
- W2023409044 cites W2963111191 @default.
- W2023409044 cites W3099561580 @default.
- W2023409044 cites W3101712865 @default.
- W2023409044 cites W3102158157 @default.
- W2023409044 cites W3102275364 @default.
- W2023409044 cites W3102656824 @default.
- W2023409044 cites W3103460433 @default.
- W2023409044 cites W3104190564 @default.
- W2023409044 cites W3104623136 @default.
- W2023409044 cites W3104695183 @default.
- W2023409044 cites W3104790781 @default.
- W2023409044 cites W3105027294 @default.
- W2023409044 doi "https://doi.org/10.1021/jp508635n" @default.
- W2023409044 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25347199" @default.
- W2023409044 hasPublicationYear "2014" @default.
- W2023409044 type Work @default.
- W2023409044 sameAs 2023409044 @default.
- W2023409044 citedByCount "13" @default.
- W2023409044 countsByYear W20234090442015 @default.
- W2023409044 countsByYear W20234090442017 @default.
- W2023409044 countsByYear W20234090442018 @default.
- W2023409044 countsByYear W20234090442019 @default.
- W2023409044 countsByYear W20234090442020 @default.
- W2023409044 countsByYear W20234090442021 @default.
- W2023409044 countsByYear W20234090442022 @default.
- W2023409044 countsByYear W20234090442023 @default.
- W2023409044 crossrefType "journal-article" @default.
- W2023409044 hasAuthorship W2023409044A5044618101 @default.
- W2023409044 hasAuthorship W2023409044A5085437975 @default.
- W2023409044 hasBestOaLocation W20234090442 @default.
- W2023409044 hasConcept C121332964 @default.
- W2023409044 hasConcept C121864883 @default.
- W2023409044 hasConcept C122865956 @default.
- W2023409044 hasConcept C124589349 @default.
- W2023409044 hasConcept C159467904 @default.
- W2023409044 hasConcept C166014724 @default.
- W2023409044 hasConcept C178790620 @default.
- W2023409044 hasConcept C185592680 @default.
- W2023409044 hasConcept C192562407 @default.
- W2023409044 hasConcept C521977710 @default.
- W2023409044 hasConcept C55493867 @default.
- W2023409044 hasConcept C62520636 @default.
- W2023409044 hasConcept C72319582 @default.
- W2023409044 hasConcept C89464430 @default.
- W2023409044 hasConcept C94406020 @default.
- W2023409044 hasConcept C97355855 @default.