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- W2023409631 abstract "The critical micelle concentration (CMC) of aqueous sodium dodecyl sulfate (SDS) solutions decreases, upon the addition of 1-alcohols. There is a linear relation between the carbon number of the alcohols and the slope of the CMC decrease with alcohol concentration. The slope of the CMC decrease with alcohol concentration is found to relate linearly to ΔGp° for the standard free energy change of penetration of the alcohol from the aqueous to the micellar phases. For the alcohols the following equation was obtained. In CMC = −0.82Xa − 8.84, where Xa is the mole fraction of the alcohol in the micellar phase. The coefficient −0.82 is related to the interaction of surfactants and additives. The factor which governs the CMC is the mole fraction of alcohol in the micellar phase independent of the kind of alcohol. The chemical potential of the micelle decreases because the electrical potential of the micelle decreases when alcohol moves from the aqueous to the micellar phase. The effect of the alcohols on the CMC decrease has been elucidated numerically." @default.
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- W2023409631 date "1978-03-01" @default.
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- W2023409631 title "Effect of alcohols on the critical micelle concentration decrease in the aqueous sodium dodecyl sulfate solution" @default.
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- W2023409631 doi "https://doi.org/10.1016/s0021-9797(78)80005-8" @default.
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