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- W2023421867 abstract "Base hydrolysis and aquation of trans-[Co(NH3)4(NH2CH3)X]2+ (where X = Cl, Br and NO3) complexes are reported. Both types of reactions are four to eight times faster than the corresponding reactions for [Co(NH3)5X]2+ complexes. The positive activation entropies of the base hydrolysis for all the studied trans-[Co(NH3)4(NH2CH3)X]2+ ions and the stereochemistry of the hydroxo products are indicative of a dissociative conjugate base, Dcb, mechanism. The steric course of the base hydrolysis differs significantly from that of the parent penta-ammines. For the aquation reactions, the activation enthalpies of the trans-methylamine and penta-ammine complexes are similar, while the activation entropies are more positive (or less negative) for the former. These results are interpreted in terms of an Id mechanism." @default.
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- W2023421867 date "1996-06-01" @default.
- W2023421867 modified "2023-09-23" @default.
- W2023421867 title "Base hydrolysis and aquation of trans-methyl-substituted acidopenta-amminecobalt(III) complexes" @default.
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- W2023421867 doi "https://doi.org/10.1016/0277-5387(95)00473-4" @default.
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