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- W2023430079 abstract "Access to new chiral reagents: The first catalytic enantioselective synthesis of axially chiral N,N-dialkylbenzamides was developed in high yields with outstanding enantiomeric excesses (>99 % ee) by aromatization through a cationic rhodium(I)/segphos or binap complex catalyzed [2+2+2] cycloaddition of 1,6-diynes with N,N-dialkylalkynylamides (see scheme). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2111/2008/z800953_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W2023430079 date "2008-07-21" @default.
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- W2023430079 title "Highly Enantioselective Synthesis of<i>N</i>,<i>N-</i>Dialkylbenzamides with Aryl-Carbonyl Axial Chirality by Rhodium-Catalyzed [2+2+2] Cycloaddition" @default.
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- W2023430079 doi "https://doi.org/10.1002/chem.200800953" @default.
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