Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023430830> ?p ?o ?g. }
- W2023430830 endingPage "10355" @default.
- W2023430830 startingPage "10347" @default.
- W2023430830 abstract "We report the first low temperature measurements on the collisional relaxation of toluene molecules initially containing high amounts of internal excitation. These highly excited toluene molecules are generated by photoisomerization of cycloheptatriene molecules that are excited by irradiation with the output of an excimer laser operating at 248 nm. These measurements have been performed on very dilute mixtures of cycloheptatriene in He, Ar, or N2 carrier gas in a CRESU (Cinétique de Réaction en Ecoulement Supersonique Uniforme) apparatus. Collisional relaxation of the excited toluene molecules is followed by observing their time-resolved infrared fluorescence. Analysis of the results allows us to infer how the average energy removed per collision, 〈〈ΔE〉〉, varies with the average energy contained in the toluene molecule, 〈〈E〉〉, for toluene−He collisions down to 38 K, for toluene−Ar collisions down to 112 K, and for toluene−N2 collisions down to 74 K. In no case is the variation of 〈〈ΔE〉〉 with temperature strong. However, in the case of toluene−He, the trend is for 〈〈ΔE〉〉 to decline with temperature, whereas for toluene−Ar and toluene−N2 〈〈ΔE〉〉 is essentially independent of temperature. It is suggested that these results may reflect the relative influence of the van der Waals forces in inducing energy transfer." @default.
- W2023430830 created "2016-06-24" @default.
- W2023430830 creator A5027449777 @default.
- W2023430830 creator A5028372022 @default.
- W2023430830 creator A5054602482 @default.
- W2023430830 date "2000-08-08" @default.
- W2023430830 modified "2023-10-16" @default.
- W2023430830 title "Vibrational Relaxation of Highly Excited Toluene in Collisions with He, Ar, and N<sub>2</sub> at Temperatures down to 38 K" @default.
- W2023430830 cites W1967052546 @default.
- W2023430830 cites W1967252924 @default.
- W2023430830 cites W1971664182 @default.
- W2023430830 cites W1973286180 @default.
- W2023430830 cites W1974515356 @default.
- W2023430830 cites W1976051221 @default.
- W2023430830 cites W1977501608 @default.
- W2023430830 cites W1978402463 @default.
- W2023430830 cites W1983929668 @default.
- W2023430830 cites W1985496976 @default.
- W2023430830 cites W1986059028 @default.
- W2023430830 cites W1988313688 @default.
- W2023430830 cites W1989043771 @default.
- W2023430830 cites W1994165707 @default.
- W2023430830 cites W1998167724 @default.
- W2023430830 cites W2001606874 @default.
- W2023430830 cites W2006215166 @default.
- W2023430830 cites W2011341090 @default.
- W2023430830 cites W2016901412 @default.
- W2023430830 cites W2018843966 @default.
- W2023430830 cites W2025213850 @default.
- W2023430830 cites W2028388852 @default.
- W2023430830 cites W2029644923 @default.
- W2023430830 cites W2031466809 @default.
- W2023430830 cites W2040340647 @default.
- W2023430830 cites W2044865834 @default.
- W2023430830 cites W2053123865 @default.
- W2023430830 cites W2056670586 @default.
- W2023430830 cites W2059175948 @default.
- W2023430830 cites W2060809271 @default.
- W2023430830 cites W2071605320 @default.
- W2023430830 cites W2072126646 @default.
- W2023430830 cites W2073692817 @default.
- W2023430830 cites W2078740339 @default.
- W2023430830 cites W2085050121 @default.
- W2023430830 cites W2085190619 @default.
- W2023430830 cites W2085817469 @default.
- W2023430830 cites W2089659390 @default.
- W2023430830 cites W2090599541 @default.
- W2023430830 cites W2091766753 @default.
- W2023430830 cites W2105996456 @default.
- W2023430830 cites W2106408516 @default.
- W2023430830 cites W2120726189 @default.
- W2023430830 cites W2151739653 @default.
- W2023430830 cites W2152290052 @default.
- W2023430830 cites W2345879730 @default.
- W2023430830 cites W2915893054 @default.
- W2023430830 doi "https://doi.org/10.1021/jp0014216" @default.
- W2023430830 hasPublicationYear "2000" @default.
- W2023430830 type Work @default.
- W2023430830 sameAs 2023430830 @default.
- W2023430830 citedByCount "24" @default.
- W2023430830 countsByYear W20234308302012 @default.
- W2023430830 countsByYear W20234308302013 @default.
- W2023430830 countsByYear W20234308302015 @default.
- W2023430830 countsByYear W20234308302017 @default.
- W2023430830 countsByYear W20234308302019 @default.
- W2023430830 countsByYear W20234308302021 @default.
- W2023430830 crossrefType "journal-article" @default.
- W2023430830 hasAuthorship W2023430830A5027449777 @default.
- W2023430830 hasAuthorship W2023430830A5028372022 @default.
- W2023430830 hasAuthorship W2023430830A5054602482 @default.
- W2023430830 hasConcept C113196181 @default.
- W2023430830 hasConcept C121332964 @default.
- W2023430830 hasConcept C126061179 @default.
- W2023430830 hasConcept C15744967 @default.
- W2023430830 hasConcept C178790620 @default.
- W2023430830 hasConcept C181500209 @default.
- W2023430830 hasConcept C184779094 @default.
- W2023430830 hasConcept C185592680 @default.
- W2023430830 hasConcept C2776029896 @default.
- W2023430830 hasConcept C2778142098 @default.
- W2023430830 hasConcept C2779023668 @default.
- W2023430830 hasConcept C32909587 @default.
- W2023430830 hasConcept C62520636 @default.
- W2023430830 hasConcept C74561354 @default.
- W2023430830 hasConcept C75473681 @default.
- W2023430830 hasConcept C77805123 @default.
- W2023430830 hasConcept C83581075 @default.
- W2023430830 hasConcept C91881484 @default.
- W2023430830 hasConceptScore W2023430830C113196181 @default.
- W2023430830 hasConceptScore W2023430830C121332964 @default.
- W2023430830 hasConceptScore W2023430830C126061179 @default.
- W2023430830 hasConceptScore W2023430830C15744967 @default.
- W2023430830 hasConceptScore W2023430830C178790620 @default.
- W2023430830 hasConceptScore W2023430830C181500209 @default.
- W2023430830 hasConceptScore W2023430830C184779094 @default.
- W2023430830 hasConceptScore W2023430830C185592680 @default.
- W2023430830 hasConceptScore W2023430830C2776029896 @default.
- W2023430830 hasConceptScore W2023430830C2778142098 @default.