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- W2023447281 abstract "Abstract Acylases have shown several promiscuities towards non-natural substrates. For example, acylases have been proved to be able to catalyze Markovnikov addition of N -heterocycles to vinyl esters recently. Some interesting and unexplainable observations drew our attention, and the acylase-catalyzed Markovnikov addition was investigated further in this paper. We detected an acylation product in the reaction and found that acetaldehyde was able to improve the reaction rate. Moreover, Markovnikov adduct could be formed using isopropenyl acetate or 2,2,2-trifluoro-ethyl acetate as substrates in the presence of acetaldehyde. Based on these results, it was proposed that the so-called acylase-catalyzed Markovnikov addition actually consisted of three steps identified as acylation, hemiaminal intermediate formation and transesterification. This discovery revealed that the promiscuity of acylase for Markovnikov addition was pseudo -promiscuity." @default.
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- W2023447281 date "2011-12-01" @default.
- W2023447281 modified "2023-10-16" @default.
- W2023447281 title "New view of acylase promiscuity: An extended study on the acylase-catalyzed Markovnikov addition" @default.
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- W2023447281 doi "https://doi.org/10.1016/j.molcatb.2011.08.002" @default.
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