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- W2023449803 abstract "The photoelectron spectrum of CeO− exhibits what appears to be a single predominant electronic transition over an energy range in which numerous close-lying electronic states of CeO neutral are well known. The photoelectron spectrum of Ce(OH)2−, a molecule in which the Ce atom shares the same formal oxidation state as the Ce atom in CeO−, also exhibits what appears to be a single transition. From the spectra, the adiabatic electron affinities of CeO and Ce(OH)2 are determined to be 0.936 ± 0.007 eV and 0.69 ± 0.03 eV, respectively. From the electron affinity of CeO, the CeO− bond dissociation energy was determined to be 7.7 eV, 0.5 eV lower than the neutral bond dissociation energy. The ground state orbital occupancies of both CeO− and Ce(OH)2− are calculated to have 4f 6s2 Ce+ superconfigurations, with open-shell states having 4f5d6s superconfiguration predicted to be over 1 eV higher in energy. Low-intensity transitions observed at higher electron binding energies in the spectrum of CeO− are tentatively assigned to the 1Σ+ (Ω = 0) state of CeO with the Ce+2ߙ6s2 superconfiguration." @default.
- W2023449803 created "2016-06-24" @default.
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- W2023449803 date "2015-02-11" @default.
- W2023449803 modified "2023-09-26" @default.
- W2023449803 title "Photoelectron spectra of CeO− and Ce(OH)2−" @default.
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- W2023449803 doi "https://doi.org/10.1063/1.4907714" @default.
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