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• W2023450287 endingPage "6861" @default.
• W2023450287 startingPage "6851" @default.
• W2023450287 abstract "Two new heterobimetallic porous coordination polymers with the formula [Fe(TPT)2/3{MI(CN)2}2]⋅nSolv (TPT=[(2,4,6-tris(4-pyridyl)-1,3,5-triazine]; MI=Ag (nSolv=0, 1 MeOH, 2 CH2Cl2), Au (nSolv=0, 2 CH2Cl2)) have been synthesized and their crystal structures were determined at 120 K and 293 K by single-crystal X-ray analysis. These structures crystallized in the trigonal R-3m space group. The FeII ion resides at an inversion centre that defines a [FeN6] coordination core. Four dicyanometallate groups coordinate at the equatorial positions, whilst the axial positions are occupied by the TPT ligand. Each TPT ligand is centred in a ternary axis and bridges three crystallographically equivalent FeII ions, whilst each dicyanometallate group bridges two crystallographically equivalent FeII ions that define a 3D network with the topology of NbO. There are two such networks, which interpenetrate each other, thereby giving rise to large spaces in which very labile solvent molecules are included (CH2Cl2 or MeOH). Crystallographic analysis confirmed the reversible structural changes that were associated with the occurrence of spin-crossover behaviour at the FeII ions, the most significant structural variation being the change in unit-cell volume (about 59 Å3 per FeII ion). The spin-crossover behaviour has been monitored by means of thermal dependence of the magnetic properties, Mössbauer spectroscopy, and calorimetry." @default.
• W2023450287 created "2016-06-24" @default.
• W2023450287 creator A5013215305 @default.
• W2023450287 creator A5060059837 @default.
• W2023450287 creator A5069408164 @default.
• W2023450287 creator A5075382599 @default.
• W2023450287 creator A5089288840 @default.
• W2023450287 date "2013-04-09" @default.
• W2023450287 modified "2023-10-18" @default.
• W2023450287 title "[Fe(TPT)_2/3{M^I(CN)₂}₂]⋅<i>n</i>Solv (M^I=Ag, Au): New Bimetallic Porous Coordination Polymers with Spin-Crossover Properties" @default.
• W2023450287 cites W180326383 @default.
• W2023450287 cites W1917142697 @default.
• W2023450287 cites W1967637823 @default.
• W2023450287 cites W1968030025 @default.
• W2023450287 cites W1968352183 @default.
• W2023450287 cites W1971471404 @default.
• W2023450287 cites W1975319963 @default.
• W2023450287 cites W1975573228 @default.
• W2023450287 cites W1976591333 @default.
• W2023450287 cites W1977761176 @default.
• W2023450287 cites W1980464562 @default.
• W2023450287 cites W1982432013 @default.
• W2023450287 cites W1983563748 @default.
• W2023450287 cites W1985613222 @default.
• W2023450287 cites W1989762902 @default.
• W2023450287 cites W1993275801 @default.
• W2023450287 cites W1994228620 @default.
• W2023450287 cites W1999460172 @default.
• W2023450287 cites W1999937609 @default.
• W2023450287 cites W2000546824 @default.
• W2023450287 cites W2000703488 @default.
• W2023450287 cites W2004364435 @default.
• W2023450287 cites W2005936801 @default.
• W2023450287 cites W2006413992 @default.
• W2023450287 cites W2008105858 @default.
• W2023450287 cites W2013633035 @default.
• W2023450287 cites W2014850613 @default.
• W2023450287 cites W2015476614 @default.
• W2023450287 cites W2018848253 @default.
• W2023450287 cites W2022167379 @default.
• W2023450287 cites W2023686222 @default.
• W2023450287 cites W2025557093 @default.
• W2023450287 cites W2041610734 @default.
• W2023450287 cites W2044245133 @default.
• W2023450287 cites W2044409058 @default.
• W2023450287 cites W2046193699 @default.
• W2023450287 cites W2050867536 @default.
• W2023450287 cites W2060048911 @default.
• W2023450287 cites W2060910908 @default.
• W2023450287 cites W2072246225 @default.
• W2023450287 cites W2072894057 @default.
• W2023450287 cites W2073092764 @default.
• W2023450287 cites W2073380218 @default.
• W2023450287 cites W2073530175 @default.
• W2023450287 cites W2073672728 @default.
• W2023450287 cites W2078763871 @default.
• W2023450287 cites W2082355199 @default.
• W2023450287 cites W2084382151 @default.
• W2023450287 cites W2089238765 @default.
• W2023450287 cites W2093780561 @default.
• W2023450287 cites W2100280379 @default.
• W2023450287 cites W2105083971 @default.
• W2023450287 cites W2108659542 @default.
• W2023450287 cites W2108712263 @default.
• W2023450287 cites W2110993530 @default.
• W2023450287 cites W2117591226 @default.
• W2023450287 cites W2117944336 @default.
• W2023450287 cites W2123432815 @default.
• W2023450287 cites W2126768350 @default.
• W2023450287 cites W2129325875 @default.
• W2023450287 cites W2131350133 @default.
• W2023450287 cites W2132788467 @default.
• W2023450287 cites W2137933939 @default.
• W2023450287 cites W2140358568 @default.
• W2023450287 cites W2143753629 @default.
• W2023450287 cites W2143997640 @default.
• W2023450287 cites W2144414872 @default.
• W2023450287 cites W2146230953 @default.
• W2023450287 cites W2147012995 @default.
• W2023450287 cites W2153592438 @default.
• W2023450287 cites W2155865512 @default.
• W2023450287 cites W2160251855 @default.
• W2023450287 cites W2166068045 @default.
• W2023450287 cites W2171192007 @default.
• W2023450287 cites W2172030852 @default.
• W2023450287 cites W2316441214 @default.
• W2023450287 cites W2317865481 @default.
• W2023450287 cites W2324809970 @default.
• W2023450287 cites W2331005312 @default.
• W2023450287 cites W2332443737 @default.
• W2023450287 cites W2949436959 @default.
• W2023450287 cites W4211133177 @default.
• W2023450287 cites W4230500890 @default.
• W2023450287 cites W4232452018 @default.
• W2023450287 cites W4239092610 @default.
• W2023450287 cites W4239749305 @default.
• W2023450287 cites W4241705297 @default.
• W2023450287 cites W4243392185 @default.

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