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• W2023452607 abstract "Abstract Yttrium‐group heavy rare‐earth sesquioxide (RE 2 O 3 , RE=Y, Dy, Ho, Er) nanobelts were successfully fabricated by thermolysis of solid RE(NO 3 ) 3 ⋅ x H 2 O in a dodecylamine/1‐octadecene mixed solvent system. The synthetic principle is based on separating the nucleation and growth processes by utilizing the poor solubility of RE(NO 3 ) 3 ⋅ χ H 2 O in the solvent mixture and the heat‐transportation difference between the liquid and solid. By using dodecylamine, RE 2 O 3 nanobelts can be readily obtained. X‐ray diffraction (XRD) analysis shows that the synthesized RE 2 O 3 nanobelts are body‐centered cubic and crystalline. Field‐emission scanning electron microscopy (FE‐SEM), transmission electron microscopy (TEM), selective‐area electron diffraction (SAED), and high‐resolution transmission electron microscopy (HR‐TEM) demonstrate that the synthesized RE 2 O 3 compounds possess regular geometric structure (beltlike) with perfect crystallinity. Preliminary experimental results prove that the dodecylamine plays a key role in the formation of RE 2 O 3 nanobelts and cannot be replaced by other surfactants. Furthermore, this method can be extended to the synthesis of RE 2 O 3 nanobelt/metal nanocrystal nanocomposites and ABO 3 (A=Y, Dy, Ho, Er; B=Al) and A 3 B 5 O 12 (A=Y, Dy, Ho, Er; B=Al)‐type ternary oxide nanobelts, using mixed‐metal nitrate salts in the correct stoichiometry instead of single rare‐earth nitrates." @default.
• W2023452607 created "2016-06-24" @default.
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• W2023452607 date "2008-02-01" @default.
• W2023452607 modified "2023-10-18" @default.
• W2023452607 title "Large-Scale Synthesis of Single-Crystalline RE2O3 (RE=Y, Dy, Ho, Er) Nanobelts by a Solid–Liquid-Phase Chemical Route" @default.
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• W2023452607 doi "https://doi.org/10.1002/chem.200700808" @default.
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