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- W2023465708 abstract "Phosphorylation of 4- and 1-substituted 1,2,4-triazoles with PCl3, PhPCl2, Ph2PCl, and (Et2N)2 PCl was carried out. A novel phosphorus-containing condensed heterocyclic system (18, 23) was constructed by the reactions of 2-(1H-1,2,4-triazol-1-yl)-1-(4-chlorophenylcarboxamido)-5-trifluoromethylbenzene with PBr3 and PhPBr2. Treatment of the bromophosphonite 18 with an excess of morpholine in the presence of sulfur resulted in a diazaphosphinine ring opening and provided functionalized 1H-1,2,4-triazol-5-ylphosphonic acid derivatives 21 and 22. © 2002 Wiley Periodicals, Inc. Heteroatom Chem 13:146–152, 2002; Published online in Wiley Interscience (www.interscience.wiley.com). DOI 10.1002/hc.10010" @default.
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- W2023465708 date "2010-05-20" @default.
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- W2023465708 title "ChemInform Abstract: C-Phosphorylation of 1,2,4-Triazoles with Phosphorus(III) Halides. Synthesis of 4,5-Dihydrobenzo[e][1,2,4]triazolo[5,1-c][1,4,2]diazaphosphinine Derivatives." @default.
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