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• W2023473424 startingPage "9494" @default.
• W2023473424 abstract "The first solid-state structures of ortho-sulfonated monoazo dyestuffs are reported and compared to those of their para- and meta-sulfonated analogues. The structures of the 16 Na, K, Cs, Mg, Ca, Sr, and Ba ortho-sulfonated salts are found to have fewer MO3S bonds than their isomeric equivalents and this in turn means that the metal type is no longer the prime indicator of which structural type will be adopted. MO3S bonds are replaced by MOH2, MHOR and M–π interactions, apparently for steric reasons. As well as new bonding motifs, the changed dye shape also leads to new packing motifs. The simple organic/inorganic layering ubiquitous to the para- and meta-sulfonated dye salt structures is replaced by variations (organic bilayers, inorganic channels), each of which correlates with a different degree of molecular planarity in the sulfonated azo dye anion." @default.
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• W2023473424 date "2009-09-21" @default.
• W2023473424 modified "2023-09-27" @default.
• W2023473424 title "Supramolecular Structure in s-Block Metal Complexes of Sulfonated Monoazo Dyes: Discrepant Packing and Bonding Behavior of<i>ortho-</i>Sulfonated Azo Dyes" @default.
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• W2023473424 doi "https://doi.org/10.1002/chem.200802555" @default.
• W2023473424 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19658126" @default.
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