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- W2023477757 abstract "Development of new organosilane reagents bearing C-centered chirality where the stereocenter is fully substituted, and their use in the stereocontrolled synthesis of cis- and trans-dihydropyrans containing a trisubstituted olefin is described. The reagents participate in Lewis acid promoted [4+2]-annulations providing useful levels of selectivity with both aliphatic and aromatic aldehydes. A stereoselective synthesis of the C1a-C10 fragment of kendomycin (1) is also described." @default.
- W2023477757 created "2016-06-24" @default.
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- W2023477757 date "2005-03-22" @default.
- W2023477757 modified "2023-09-26" @default.
- W2023477757 title "Stereocontrolled [4+2]-Annulation Accessing Dihydropyrans: Synthesis of the C1a-C10 Fragment of Kendomycin" @default.
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- W2023477757 doi "https://doi.org/10.1021/ol0501875" @default.
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