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- W2023478234 abstract "Tetrahydrofuran/toluene solutions of (nacnac)TiCl2 (nacnac− = [ArNC(tBu)]2CH, Ar = 2,6-iPr2C6H3) react readily with KC8 to afford the titanium imide (ArN(tBu)CCHC(tBu))TiNAr(THF)Cl (1) in 67% isolated yield. Complex 1 forms from the two-electron reductive C–N bond cleavage of the β-diketiminate ligand. Likewise, reduction of (nacnac)TiCl(NHAr) (2), prepared in 85% yield from (nacnac)TiCl2 and LiNHAr, with KC8 results in formation of the imide-anilide analogue (ArN(tBu)CCHC(tBu))TiNAr(NHAr) (3) in 88% yield. Another reductant such as LitBu (3 equiv.) reacts cleanly with the precursor (nacnac)TiCl2 to afford the alkylidene-ate complex [Li(Et2O)][(ArN(tBu)CCHC(tBu))TiNAr(Et2O)] (4), in 81% yield. Complexes 1–4 have been characterized by 1H and 13C NMR spectra as well as single-crystal X-ray diffraction analysis. Plausible mechanisms to formation of compounds 1, 3 and 4 are also presented and discussed." @default.
- W2023478234 created "2016-06-24" @default.
- W2023478234 creator A5051328139 @default.
- W2023478234 creator A5073811804 @default.
- W2023478234 creator A5080206718 @default.
- W2023478234 date "2007-01-01" @default.
- W2023478234 modified "2023-10-17" @default.
- W2023478234 title "Reductive C–N bond cleavage of the NCCCN β-diketiminate backbone: A direct approach to azabutadienyl and alkylidene-anilide scaffolds" @default.
- W2023478234 cites W1837430940 @default.
- W2023478234 cites W1859441410 @default.
- W2023478234 cites W1903642103 @default.
- W2023478234 cites W1965631058 @default.
- W2023478234 cites W1966051519 @default.
- W2023478234 cites W1966415697 @default.
- W2023478234 cites W1967563275 @default.
- W2023478234 cites W1967984957 @default.
- W2023478234 cites W1968191262 @default.
- W2023478234 cites W1969111261 @default.
- W2023478234 cites W1971499434 @default.
- W2023478234 cites W1971981906 @default.
- W2023478234 cites W1972244400 @default.
- W2023478234 cites W1973045139 @default.
- W2023478234 cites W1975066352 @default.
- W2023478234 cites W1975848173 @default.
- W2023478234 cites W1978900507 @default.
- W2023478234 cites W1983372190 @default.
- W2023478234 cites W1984605747 @default.
- W2023478234 cites W1985171442 @default.
- W2023478234 cites W1985420479 @default.
- W2023478234 cites W1988594523 @default.
- W2023478234 cites W1992074406 @default.
- W2023478234 cites W1993403734 @default.
- W2023478234 cites W1994888707 @default.
- W2023478234 cites W1996151069 @default.
- W2023478234 cites W1996707110 @default.
- W2023478234 cites W1997374390 @default.
- W2023478234 cites W1997869520 @default.
- W2023478234 cites W1998388656 @default.
- W2023478234 cites W2000466466 @default.
- W2023478234 cites W2001011492 @default.
- W2023478234 cites W2003076245 @default.
- W2023478234 cites W2003121173 @default.
- W2023478234 cites W2012556554 @default.
- W2023478234 cites W2013629425 @default.
- W2023478234 cites W2013686593 @default.
- W2023478234 cites W2017982765 @default.
- W2023478234 cites W2022657029 @default.
- W2023478234 cites W2025561917 @default.
- W2023478234 cites W2027822392 @default.
- W2023478234 cites W2028713159 @default.
- W2023478234 cites W2029658403 @default.
- W2023478234 cites W2032204723 @default.
- W2023478234 cites W2041043000 @default.
- W2023478234 cites W2041190978 @default.
- W2023478234 cites W2041546233 @default.
- W2023478234 cites W2042061343 @default.
- W2023478234 cites W2042556792 @default.
- W2023478234 cites W2043510643 @default.
- W2023478234 cites W2046663248 @default.
- W2023478234 cites W2049536381 @default.
- W2023478234 cites W2050571926 @default.
- W2023478234 cites W2054149576 @default.
- W2023478234 cites W2056396660 @default.
- W2023478234 cites W2056936134 @default.
- W2023478234 cites W2059212126 @default.
- W2023478234 cites W2060287442 @default.
- W2023478234 cites W2063096811 @default.
- W2023478234 cites W2063184595 @default.
- W2023478234 cites W2063547496 @default.
- W2023478234 cites W2064814454 @default.
- W2023478234 cites W2064978746 @default.
- W2023478234 cites W2074515548 @default.
- W2023478234 cites W2078470879 @default.
- W2023478234 cites W2079262904 @default.
- W2023478234 cites W2081054814 @default.
- W2023478234 cites W2081673387 @default.
- W2023478234 cites W2082189380 @default.
- W2023478234 cites W2084449323 @default.
- W2023478234 cites W2086732303 @default.
- W2023478234 cites W2093239268 @default.
- W2023478234 cites W2093601046 @default.
- W2023478234 cites W2093947989 @default.
- W2023478234 cites W2099037802 @default.
- W2023478234 cites W2105800460 @default.
- W2023478234 cites W2107108579 @default.
- W2023478234 cites W2153725588 @default.
- W2023478234 cites W2161428240 @default.
- W2023478234 cites W2170793973 @default.
- W2023478234 cites W2949178448 @default.
- W2023478234 doi "https://doi.org/10.1016/j.ica.2006.07.045" @default.
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