Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023483495> ?p ?o ?g. }
Showing items 1 to 87 of
87
with 100 items per page.
- W2023483495 endingPage "5711" @default.
- W2023483495 startingPage "5707" @default.
- W2023483495 abstract "Unlike bis(diethylamino)organosilylboranes, bis(diisopropylamino)organosilylboranes, which have UV absorption at longer wavelength than 300 nm, undergo photolysis to afford pairs of an organosilyl radical and a bis(diisopropylamino)boryl radical by homolytic scission of the silicon-boron bonds. Generation of organosilyl radical and organoboryl radical was confirmed by trapping experiments using TEMPO (2,2,6,6-tetramethylpiperidine N-oxyl). The organosilyl radical thus generated induces not only silylation of mono-olefins and silylative cyclization of dienes but also polymerization to afford polymers bearing organosilyl termini. On the other hand, the bis(diisopropylamino)boryl radical generated is not incorporated into the olefin adducts." @default.
- W2023483495 created "2016-06-24" @default.
- W2023483495 creator A5034939239 @default.
- W2023483495 creator A5061403783 @default.
- W2023483495 date "2000-08-12" @default.
- W2023483495 modified "2023-10-13" @default.
- W2023483495 title "New Generation of Organosilyl Radicals by Photochemically Induced Homolytic Cleavage of Silicon−Boron Bonds" @default.
- W2023483495 cites W1969862888 @default.
- W2023483495 cites W1978783982 @default.
- W2023483495 cites W1987143702 @default.
- W2023483495 cites W1987564066 @default.
- W2023483495 cites W2011822711 @default.
- W2023483495 cites W2038300936 @default.
- W2023483495 cites W2071982166 @default.
- W2023483495 cites W2095491971 @default.
- W2023483495 cites W2103540105 @default.
- W2023483495 cites W2121134349 @default.
- W2023483495 cites W2153941030 @default.
- W2023483495 cites W2162512315 @default.
- W2023483495 cites W2324475751 @default.
- W2023483495 cites W2949196684 @default.
- W2023483495 cites W3005187241 @default.
- W2023483495 doi "https://doi.org/10.1021/jo000547w" @default.
- W2023483495 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/10970314" @default.
- W2023483495 hasPublicationYear "2000" @default.
- W2023483495 type Work @default.
- W2023483495 sameAs 2023483495 @default.
- W2023483495 citedByCount "60" @default.
- W2023483495 countsByYear W20234834952012 @default.
- W2023483495 countsByYear W20234834952013 @default.
- W2023483495 countsByYear W20234834952014 @default.
- W2023483495 countsByYear W20234834952015 @default.
- W2023483495 countsByYear W20234834952016 @default.
- W2023483495 countsByYear W20234834952017 @default.
- W2023483495 countsByYear W20234834952018 @default.
- W2023483495 countsByYear W20234834952019 @default.
- W2023483495 countsByYear W20234834952020 @default.
- W2023483495 countsByYear W20234834952021 @default.
- W2023483495 countsByYear W20234834952022 @default.
- W2023483495 countsByYear W20234834952023 @default.
- W2023483495 crossrefType "journal-article" @default.
- W2023483495 hasAuthorship W2023483495A5034939239 @default.
- W2023483495 hasAuthorship W2023483495A5061403783 @default.
- W2023483495 hasConcept C139066938 @default.
- W2023483495 hasConcept C161790260 @default.
- W2023483495 hasConcept C175689099 @default.
- W2023483495 hasConcept C178790620 @default.
- W2023483495 hasConcept C185592680 @default.
- W2023483495 hasConcept C188027245 @default.
- W2023483495 hasConcept C3044715 @default.
- W2023483495 hasConcept C501308230 @default.
- W2023483495 hasConcept C5304478 @default.
- W2023483495 hasConcept C54582936 @default.
- W2023483495 hasConcept C75473681 @default.
- W2023483495 hasConceptScore W2023483495C139066938 @default.
- W2023483495 hasConceptScore W2023483495C161790260 @default.
- W2023483495 hasConceptScore W2023483495C175689099 @default.
- W2023483495 hasConceptScore W2023483495C178790620 @default.
- W2023483495 hasConceptScore W2023483495C185592680 @default.
- W2023483495 hasConceptScore W2023483495C188027245 @default.
- W2023483495 hasConceptScore W2023483495C3044715 @default.
- W2023483495 hasConceptScore W2023483495C501308230 @default.
- W2023483495 hasConceptScore W2023483495C5304478 @default.
- W2023483495 hasConceptScore W2023483495C54582936 @default.
- W2023483495 hasConceptScore W2023483495C75473681 @default.
- W2023483495 hasIssue "18" @default.
- W2023483495 hasLocation W20234834951 @default.
- W2023483495 hasLocation W20234834952 @default.
- W2023483495 hasOpenAccess W2023483495 @default.
- W2023483495 hasPrimaryLocation W20234834951 @default.
- W2023483495 hasRelatedWork W1563902804 @default.
- W2023483495 hasRelatedWork W2006913444 @default.
- W2023483495 hasRelatedWork W2016243723 @default.
- W2023483495 hasRelatedWork W2128811753 @default.
- W2023483495 hasRelatedWork W2946415609 @default.
- W2023483495 hasRelatedWork W3024802604 @default.
- W2023483495 hasRelatedWork W4242974948 @default.
- W2023483495 hasRelatedWork W4290973718 @default.
- W2023483495 hasRelatedWork W4323535369 @default.
- W2023483495 hasRelatedWork W4385264669 @default.
- W2023483495 hasVolume "65" @default.
- W2023483495 isParatext "false" @default.
- W2023483495 isRetracted "false" @default.
- W2023483495 magId "2023483495" @default.
- W2023483495 workType "article" @default.