FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023488099> ?p ?o ?g. }

• W2023488099 endingPage "8726" @default.
• W2023488099 startingPage "8719" @default.
• W2023488099 abstract "We present a comprehensive investigation of the spatial dimensions of colloidal spherical polyelectrolyte brushes in solutions. The particles studied here consist of a solid polystyrene core of 50−100 nm radius onto which linear poly(acrylic acid) (PAA) chains are chemically grafted. The grafting is achieved through photo-emulsionpolymerization in which radicals are generated on the surface of the core particles. This procedure leads to a dense brush of PAA chains chemically fixed on the surface of the core particles. The hydrodynamic radius RH of these particles is studied by dynamic light scattering as function of salt concentration. The chemical grafting leads to an extreme colloidal stability, and RH can be studied in KCl solutions which concentrations varying between 10-3 and 3 M. The resulting RH decreased monotonically with ionic strength. The data of RH as function of ionic strength were compared with the theory of Hariharan, Biver and Russel (Macromolecules, 1998, 31, 7514). This theory, which is based on the Daoud−Cotton model of uncharged curved brushes, describes the spherical polyelectrolyte brushes, in terms of an excluded volume parameter v and the Kuhn length lK. The local ionic strength of the brush cs is predicted to differ widely from the bulk value ca. Both v and lK depend on the local ionic strength cs as expressed through the Debye length κ-1 within the brush. Quantitative agreement of theory and experiment is achieved when the following assumptions are made: v ∝ lK2κ-1, and lK ∝ lB-1κ-2, where lB denotes the Bjerrum-length." @default.
• W2023488099 created "2016-06-24" @default.
• W2023488099 creator A5023233095 @default.
• W2023488099 creator A5079891754 @default.
• W2023488099 date "2000-08-09" @default.
• W2023488099 modified "2023-10-10" @default.
• W2023488099 title "Spatial Dimensions of Colloidal Polyelectrolyte Brushes As Determined by Dynamic Light Scattering" @default.
• W2023488099 cites W1965537738 @default.
• W2023488099 cites W1975493495 @default.
• W2023488099 cites W1978176651 @default.
• W2023488099 cites W1979018551 @default.
• W2023488099 cites W1979268619 @default.
• W2023488099 cites W1981321851 @default.
• W2023488099 cites W1982572215 @default.
• W2023488099 cites W1998523939 @default.
• W2023488099 cites W2005600260 @default.
• W2023488099 cites W2008651265 @default.
• W2023488099 cites W2021824593 @default.
• W2023488099 cites W2028912372 @default.
• W2023488099 cites W2032476367 @default.
• W2023488099 cites W2034707824 @default.
• W2023488099 cites W2036203264 @default.
• W2023488099 cites W2041151652 @default.
• W2023488099 cites W2050419878 @default.
• W2023488099 cites W2051893661 @default.
• W2023488099 cites W2054787526 @default.
• W2023488099 cites W2062507380 @default.
• W2023488099 cites W2063684249 @default.
• W2023488099 cites W2063874145 @default.
• W2023488099 cites W2065299365 @default.
• W2023488099 cites W2070399536 @default.
• W2023488099 cites W2084905196 @default.
• W2023488099 cites W2158013337 @default.
• W2023488099 cites W2162090300 @default.
• W2023488099 cites W2170359956 @default.
• W2023488099 doi "https://doi.org/10.1021/la000319x" @default.
• W2023488099 hasPublicationYear "2000" @default.
• W2023488099 type Work @default.
• W2023488099 sameAs 2023488099 @default.
• W2023488099 citedByCount "185" @default.
• W2023488099 countsByYear W20234880992012 @default.
• W2023488099 countsByYear W20234880992013 @default.
• W2023488099 countsByYear W20234880992014 @default.
• W2023488099 countsByYear W20234880992015 @default.
• W2023488099 countsByYear W20234880992016 @default.
• W2023488099 countsByYear W20234880992017 @default.
• W2023488099 countsByYear W20234880992018 @default.
• W2023488099 countsByYear W20234880992019 @default.
• W2023488099 countsByYear W20234880992020 @default.
• W2023488099 countsByYear W20234880992021 @default.
• W2023488099 countsByYear W20234880992022 @default.
• W2023488099 countsByYear W20234880992023 @default.
• W2023488099 crossrefType "journal-article" @default.
• W2023488099 hasAuthorship W2023488099A5023233095 @default.
• W2023488099 hasAuthorship W2023488099A5079891754 @default.
• W2023488099 hasConcept C121332964 @default.
• W2023488099 hasConcept C127413603 @default.
• W2023488099 hasConcept C145148216 @default.
• W2023488099 hasConcept C14631669 @default.
• W2023488099 hasConcept C147789679 @default.
• W2023488099 hasConcept C153356533 @default.
• W2023488099 hasConcept C155672457 @default.
• W2023488099 hasConcept C159467904 @default.
• W2023488099 hasConcept C171250308 @default.
• W2023488099 hasConcept C178635117 @default.
• W2023488099 hasConcept C178790620 @default.
• W2023488099 hasConcept C184651966 @default.
• W2023488099 hasConcept C184654806 @default.
• W2023488099 hasConcept C185592680 @default.
• W2023488099 hasConcept C187428577 @default.
• W2023488099 hasConcept C188027245 @default.
• W2023488099 hasConcept C192562407 @default.
• W2023488099 hasConcept C207374878 @default.
• W2023488099 hasConcept C2182769 @default.
• W2023488099 hasConcept C2777922577 @default.
• W2023488099 hasConcept C38652104 @default.
• W2023488099 hasConcept C41008148 @default.
• W2023488099 hasConcept C42360764 @default.
• W2023488099 hasConcept C521977710 @default.
• W2023488099 hasConcept C59789625 @default.
• W2023488099 hasConcept C97355855 @default.
• W2023488099 hasConceptScore W2023488099C121332964 @default.
• W2023488099 hasConceptScore W2023488099C127413603 @default.
• W2023488099 hasConceptScore W2023488099C145148216 @default.
• W2023488099 hasConceptScore W2023488099C14631669 @default.
• W2023488099 hasConceptScore W2023488099C147789679 @default.
• W2023488099 hasConceptScore W2023488099C153356533 @default.
• W2023488099 hasConceptScore W2023488099C155672457 @default.
• W2023488099 hasConceptScore W2023488099C159467904 @default.
• W2023488099 hasConceptScore W2023488099C171250308 @default.
• W2023488099 hasConceptScore W2023488099C178635117 @default.
• W2023488099 hasConceptScore W2023488099C178790620 @default.
• W2023488099 hasConceptScore W2023488099C184651966 @default.
• W2023488099 hasConceptScore W2023488099C184654806 @default.
• W2023488099 hasConceptScore W2023488099C185592680 @default.
• W2023488099 hasConceptScore W2023488099C187428577 @default.
• W2023488099 hasConceptScore W2023488099C188027245 @default.
• W2023488099 hasConceptScore W2023488099C192562407 @default.

• next