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- W2023491133 abstract "[chemical reaction: see text]. Nitroalkene (E)-1 has been synthesized to test the feasibility of an intramolecular [4 + 2] cycloaddition in a planned synthesis of daphnilactone B. This nitro olefin contains two unique structural features, a nitromethylene lactone and a pendant diene, that combine under the action of SnCl4 in a highly selective fashion to afford nitronates 2a and 2b. These products represent the correct relationship for the vicinal quaternary stereogenic centers in the core of daphnilactone B." @default.
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- W2023491133 date "2005-11-05" @default.
- W2023491133 modified "2023-09-27" @default.
- W2023491133 title "Intramolecular [4 + 2] Cycloaddition of Nitroalkenes for Construction of Vicinal Quaternary Stereocenters" @default.
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- W2023491133 doi "https://doi.org/10.1021/ol052316n" @default.
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