Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023491464> ?p ?o ?g. }
Showing items 1 to 94 of
94
with 100 items per page.
- W2023491464 endingPage "3981" @default.
- W2023491464 startingPage "3975" @default.
- W2023491464 abstract "Oxidation of PdMe(2)(L(2)) [L(2) = 2,2'-bipyridine (bpy), 1,10-phenanthroline (phen)] by diphenyl diselenide provides the first examples of stable dimethylpalladium(IV) complexes PdMe(2)(SePh)(2)(L(2)), and pallada(IV)cyclic may be similarly isolated. X-ray structural studies of the octahedral dimethylpalladium(IV) complexes and their isomorphous platinum(IV) analogues have been completed [L(2) = bpy, orthorhombic Pnma; L(2) = phen, triclinic P&onemacr;; an additional phase for PtMe(2)(SePh)(2)(phen), tetragonal, I4(1)/a]. The complexes PdMe(2)(SePh)(2)(L(2)) decompose at moderate temperatures in CDCl(3) following first-order behavior [L(2) = bpy, E(a) approximately 46 kJ mol(-)(1), DeltaS()(20 degrees C) approximately -170 J K(-)(1) mol(-)(1); L(2) = phen, E(a) approximately 36 kJ mol(-)(1), DeltaS()(20 degrees C) approximately -204 J K(-)(1) mol(-)(1)] to give ethane and Se(Ph)Me, together with small quantities of SePh(2). Similar C.C, C.O, C.S, and C.Se bond formation processes occur on decomposition of palladium(IV) species that are too unstable to be isolated on the oxidation of PdMe(2)(bpy) or by (O(2)CPh)(2) or (SPh)(2)." @default.
- W2023491464 created "2016-06-24" @default.
- W2023491464 creator A5006709826 @default.
- W2023491464 creator A5081278308 @default.
- W2023491464 creator A5082369913 @default.
- W2023491464 creator A5090203823 @default.
- W2023491464 date "1998-07-24" @default.
- W2023491464 modified "2023-10-06" @default.
- W2023491464 title "Oxidation of Complexes by (O2CPh)2 and (ER)2 (E = S, Se), Including Structures of Pd(CH2CH2CH2CH2)(SePh)2(bpy) (bpy = 2,2‘-Bipyridine) and MMe2(SePh)2(L2) (M = Pd, Pt; L2 = bpy, 1,10-Phenanthroline) and C···O and C···E Bond Formation at Palladium(IV)" @default.
- W2023491464 cites W1974893883 @default.
- W2023491464 cites W1983431040 @default.
- W2023491464 cites W1987808027 @default.
- W2023491464 cites W2024431082 @default.
- W2023491464 cites W2028239408 @default.
- W2023491464 cites W2032374776 @default.
- W2023491464 cites W2034153212 @default.
- W2023491464 cites W2075979706 @default.
- W2023491464 cites W2078965405 @default.
- W2023491464 cites W2088977168 @default.
- W2023491464 cites W2106773756 @default.
- W2023491464 cites W2147867743 @default.
- W2023491464 cites W2162917029 @default.
- W2023491464 cites W2487703711 @default.
- W2023491464 cites W3023524883 @default.
- W2023491464 doi "https://doi.org/10.1021/ic9715005" @default.
- W2023491464 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11670512" @default.
- W2023491464 hasPublicationYear "1998" @default.
- W2023491464 type Work @default.
- W2023491464 sameAs 2023491464 @default.
- W2023491464 citedByCount "83" @default.
- W2023491464 countsByYear W20234914642012 @default.
- W2023491464 countsByYear W20234914642013 @default.
- W2023491464 countsByYear W20234914642014 @default.
- W2023491464 countsByYear W20234914642015 @default.
- W2023491464 countsByYear W20234914642016 @default.
- W2023491464 countsByYear W20234914642018 @default.
- W2023491464 countsByYear W20234914642019 @default.
- W2023491464 countsByYear W20234914642020 @default.
- W2023491464 countsByYear W20234914642021 @default.
- W2023491464 countsByYear W20234914642022 @default.
- W2023491464 countsByYear W20234914642023 @default.
- W2023491464 crossrefType "journal-article" @default.
- W2023491464 hasAuthorship W2023491464A5006709826 @default.
- W2023491464 hasAuthorship W2023491464A5081278308 @default.
- W2023491464 hasAuthorship W2023491464A5082369913 @default.
- W2023491464 hasAuthorship W2023491464A5090203823 @default.
- W2023491464 hasConcept C115624301 @default.
- W2023491464 hasConcept C155647269 @default.
- W2023491464 hasConcept C161790260 @default.
- W2023491464 hasConcept C170751736 @default.
- W2023491464 hasConcept C185592680 @default.
- W2023491464 hasConcept C198819137 @default.
- W2023491464 hasConcept C37243968 @default.
- W2023491464 hasConcept C42228675 @default.
- W2023491464 hasConcept C502130503 @default.
- W2023491464 hasConcept C518104683 @default.
- W2023491464 hasConcept C55493867 @default.
- W2023491464 hasConcept C71240020 @default.
- W2023491464 hasConcept C8010536 @default.
- W2023491464 hasConceptScore W2023491464C115624301 @default.
- W2023491464 hasConceptScore W2023491464C155647269 @default.
- W2023491464 hasConceptScore W2023491464C161790260 @default.
- W2023491464 hasConceptScore W2023491464C170751736 @default.
- W2023491464 hasConceptScore W2023491464C185592680 @default.
- W2023491464 hasConceptScore W2023491464C198819137 @default.
- W2023491464 hasConceptScore W2023491464C37243968 @default.
- W2023491464 hasConceptScore W2023491464C42228675 @default.
- W2023491464 hasConceptScore W2023491464C502130503 @default.
- W2023491464 hasConceptScore W2023491464C518104683 @default.
- W2023491464 hasConceptScore W2023491464C55493867 @default.
- W2023491464 hasConceptScore W2023491464C71240020 @default.
- W2023491464 hasConceptScore W2023491464C8010536 @default.
- W2023491464 hasIssue "16" @default.
- W2023491464 hasLocation W20234914641 @default.
- W2023491464 hasLocation W20234914642 @default.
- W2023491464 hasOpenAccess W2023491464 @default.
- W2023491464 hasPrimaryLocation W20234914641 @default.
- W2023491464 hasRelatedWork W167857991 @default.
- W2023491464 hasRelatedWork W1905496214 @default.
- W2023491464 hasRelatedWork W1984051291 @default.
- W2023491464 hasRelatedWork W2003106636 @default.
- W2023491464 hasRelatedWork W2015638737 @default.
- W2023491464 hasRelatedWork W2028657378 @default.
- W2023491464 hasRelatedWork W2121789822 @default.
- W2023491464 hasRelatedWork W2392941684 @default.
- W2023491464 hasRelatedWork W2949996783 @default.
- W2023491464 hasRelatedWork W4249168586 @default.
- W2023491464 hasVolume "37" @default.
- W2023491464 isParatext "false" @default.
- W2023491464 isRetracted "false" @default.
- W2023491464 magId "2023491464" @default.
- W2023491464 workType "article" @default.