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- W2023496724 abstract "Schutz durch Abschirmung — der Porphyrinophan‐Komplex 1 , eine funktionsfähige Modellverbindung der Cytochrom‐P‐450‐Isozyme, wurde in einer 18stufigen konvergenten Synthese hergestellt. 1 katalysiert die Epoxidierung von cis ‐Stilben durch Iodosylbenzol. Der Thiolatligand in 1 ist durch die Chlorsubstituenten und die Phan‐Kette gegen oxidativen Angriff abgeschirmt, auf der gegenüberliegenden Seite des Moleküls verhindern die Naphthalingruppen und Chlorsubstituenten die Bildung eines μ‐Oxo‐ oder μ‐Peroxo‐Komplexes. magnified image" @default.
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- W2023496724 date "1997-07-18" @default.
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- W2023496724 title "Ein überbrückter Porphyrinato(thiolato)eisen(<scp>III</scp>)‐Komplex als Modell des aktiven Zentrums der Cytochrom‐P‐450‐Isozyme" @default.
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