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- W2023497659 abstract "Crystal and solution structures of the [PdII(η3-allyl)] and of the [PdII(η3-1,3-diphenylallyl)] complexes, 4 and 5, respectively, with (4S)-4-benzyl-2-[2′-(diphenylphosphino)phenyl]-4,5-dihydrooxazole (3) were determined by X-ray crystallography and 2D-NMR spectroscopy. Complex 4 proved to be disordered with both diastereoisomeric complexes in the crystal. The results of X-ray and NMR experiments demonstrate a good agreement between solution and solid-state equilibria of the two isomers. A comparison with dichloro{(4S)-2-[2′-(diphenylphosphino)phenyl]-4,5-dihydro-4-phenyloxazole-P,N}zinc(II) (2b) shows a surprising conformational stability of the coordinated phosphinooxazole ligand 3." @default.
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- W2023497659 date "1996-05-08" @default.
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- W2023497659 title "Synthesis, and Solution and Solid-State Structures of (?3-Allyl){(4S)-4-benzyl-2-[2?-(diphenylphosphino)phenyl]- 4,5-dihydrooxazole-P,N}palladium(II) Hexafluorophosphates. Comparison with Dichloro{(4S)-2-[2?-(diphenylphosphino)phenyl]-4,5-dihydro-4-phenyloxazole-P,N}zinc(II)" @default.
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- W2023497659 doi "https://doi.org/10.1002/hlca.19960790322" @default.
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