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- W2023500629 abstract "Bustin' a move: Diffusion of NO gas into crystals of [(TPP)Fe(H2O)]SO3CF3 (1) results in nitrosylation of half the number of molecules to generate [(TPP)Fe(NO)(H2O)]SO3CF3 (2). This nitrosylation reaction in the solid phase produces a dramatic movement of the porphyrins to accommodate the NO ligands. The presence of both molecules in the same crystal allows a reliable comparison of their geometric data. TPP=tetraphenylporphyrin; C black, N blue, O red." @default.
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- W2023500629 date "2011-09-12" @default.
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- W2023500629 title "Nitrosylation in a Crystal: Remarkable Movements of Iron Porphyrins Upon Binding of Nitric Oxide" @default.
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- W2023500629 doi "https://doi.org/10.1002/anie.201103329" @default.
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