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- W2023503878 abstract "After a short discussion of structure and infrared-vibration data of rutile (Section 1), the presence of protons, replaceable by deuterons, is determined by the OH and OD stretching vibration and traced to specific lattice sites (Section 2). Various reactions in hydrogen and oxygen (Section 3) and the effects of reduction on electron mobilization and the optical absorption spectrum are considered (Section 4). Absorption spectra at high temperature and quenching experiments clarify the interrelation between absorption spectra, vacancies and conductivity (Section 5). Space-charge polarization and blocking-layer effects are elucidated by dielectric relaxation spectra, discharge characteristics and the influence of prehistory and addition agents (Section 6). Electron injection into the empty conduction band transforms unreduced rutile from an insulator into a very good conductor; incandescence and thermal breakdown at low voltage results; impulse voltage produces much higher electric strength (Section 7). All observations show the extremely anisotropic conduction of unreduced rutile single crystals, with preference by orders of magnitude in the optic-axis direction, as expected from the crystal structure. This preference is being systematically destroyed by progressive reduction. Rutile is both an n- and a p-type conductor; the experiments here reported together with the facts known previously lead to a consistent picture of its properties (Section 8)." @default.
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- W2023503878 date "1962-06-01" @default.
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- W2023503878 title "Protons, dipoles, and charge carriers in rutile in rutile" @default.
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