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- W2023505496 abstract "The reactivities of the F-tert.-alkyl halides (CF3CF2CF2(CF3)2CX (1a-c: X = I, Br, Cl) towards the corresponding lithium halides LiY (2a-c: Y = I, Br, Cl), in acetonitrile, reflect the electron acceptor properties of compounds 1 and the donator strength of the anions Y−. The tertiary carbanion F-2-methylpentanide acts as the key intermediate in the formation of the main products (F-2-methyl-2-pentene, F-2-methyl- 1-pentene and F-2-hydro-2-methylpentane), and also of the halide substitution products obtained from 1a. No support for the participation of any perfluoroalkyl radical could be found." @default.
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- W2023505496 date "1991-08-01" @default.
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- W2023505496 title "Reactions of tertiary perfluoroalkyl halides with halide anions" @default.
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- W2023505496 doi "https://doi.org/10.1016/s0022-1139(00)80962-8" @default.
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