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- W2023508204 abstract "The kinetics of base hydrolysis of (αβ S)-(o-methoxy benzoato) (tetraethylenepentamine)cobalt(III) obeyed the rate law: kobs = kOH[OH−], in the range 0.05 ⩽ [OH−]T, mol dm−3 ⩽ 1.0, I = 1.0 mol dm−3, and 20.0–40.0°C. At 25°C, kOH = 13.4 ± 0.4 dm3 mol−1 s−1, ΔH≠ = 93 ± 2 kJ mol−1 and ΔS≠ = 90 ± 5 JK−1 mol−1. Several anions of varying charge and basicity, CH3CO2−, SO32−, SO42−, CO32−, C2O42−, CH2(CO2)22−, PO43−, and citrate3− had no effect on the rate while phthalate2−, NTA3−, EDTA4−, and DTPA5− accelerated the process via formation of the reactive ion pairs. The anionic (SDS), cationic (CTAB), and neutral (Triton X-100) micelles, however, retarded the reaction, the effect being in the order SDS> CTAB > Triton X-100. The importance of electrostatic and hydrophobic effects of the micelles on the selective partitioning of the reactants between the micellar and bulk aqueous pseudo-phases which control the rate are discussed. © 1994 John Wiley & Sons, Inc." @default.
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- W2023508204 title "Base hydrolysis of (?? S)-(o-methoxy benzoato) (tetraethylenepentamine) cobalt(III) ion: A comparative study of the role of ion pairs and micelles" @default.
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