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- W2023509011 abstract "Abstract Mainly through the extensive investigations of Nakagawa and coworkers, nickel peroxide has emerged as a powerful oxidant for organic compounds. For example, it has been used for the oxidation of alcohols to aldehydes or carboxylic acids,2,3 allylic hydroxyl (selectively) to the carbonyl group,4 α-ketols to α-diketones,5 α-glycols, α-ketols, α-hydroxyl and α-keto acids to cleavage products,6 aldehydes to amides or nitriles in the presence of ammonia,7 phenols to quinones,8,9 certain Schiff bases to benzoxazoles,10 amines to azo compounds or nitriles,11,12 diarylamines to hydrazines,13 carbazoles to dimers and trimers,14 hydrazones to diazo compounds,15,16 1-aminobenzotriazole to benzyne,17 N-substituted hydroxylamines to azoxy compounds,18 phenylacetonitrile to dimeric products,19 a thiouracil to a uracil derivative,20 thiols to disulfides and sulfides to sulfones,21 N-substituted phenothiazines to sulfoxides and sulfones,21 haloforms to hexahaloethanes.23" @default.
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- W2023509011 date "1975-01-01" @default.
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- W2023509011 title "Sodium Hypochlorite Reactions. III. The Catalytic Nakagawa and Related Systems" @default.
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